| Literature DB >> 7564912 |
P H Dussault1, I Q Lee, C T Eary.
Abstract
A general approach to E,E-diene hydroperoxides is described based upon photoisomerization of readily available Z,E-diene monoperoxyketals. Protection of a Z,E-diene hydroperoxide as the 2-methoxypropyl peroxyketal is followed by iodine-mediated photoisomerization to produce a mixture enriched in the E,E isomer. After chromatographic purification, deprotection of the peroxyketal with mild acid furnishes the E,E-diene hydroperoxide.Entities:
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Year: 1995 PMID： 7564912 DOI： 10.1007/BF02536994
Source DB: PubMed Journal: Lipids ISSN： 0024-4201 Impact factor: 1.880