| Literature DB >> 7161192 |
S Omoto, H Ogino, K Iwamatsu, S Inouye.
Abstract
Treatment of 9-trichloroacetylmidecamycin with aqueous alkali gave an isomer of midecamycin (neoisomidecamycin), in which one double bond underwent allylic rearrangement. The formation of neoisomacrolides was dependent on the nature of protective groups and conditions of deprotective reaction. Treatment of 9-trichloroethoxycarbonylmidecamycin with Zn/acetic acid resulted in no allylic rearrangement.Entities:
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Year: 1982 PMID： 7161192 DOI： 10.7164/antibiotics.35.1521
Source DB: PubMed Journal: J Antibiot (Tokyo) ISSN： 0021-8820 Impact factor: 2.649