A solvent extraction technique for the measurement of 222Rn at ambient air concentrations.

The high solubility of radon in cold organic solvents is exploited to extract radon directly from a sample air stream into a hexane-based liquid scintillation solution. Up to 10 l. of air is passed through 20 ml of solvent held at -78 degrees C in a bath of dry ice and acetone. The solvent is then transferred to an ordinary glass liquid scintillation vial that has been preloaded with 2 ml of concentrated fluors. A large number of samples can be prepared in a short time with minimal equipment, making it possible for field workers to conveniently collect numerous samples prior to returning to the laboratory. After allowing an interval of at least 3 hr after processing for radon daughter ingrowth, the vials are counted on an unmodified liquid scintillation system with a narrow window set around the radon and polonium alpha peaks. The large sample volume more than compensates for the relatively high alpha background of liquid scintillators. Relevant theoretical considerations and alternate sampling strategies are discussed.