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Literature DB >> 4297644

Cyanovinyl phosphate: a prebiological phosphorylating agent?

Abstract

Cyanovinyl phosphate may be prepared by the addition reaction of phosphate to cyanoacetylene. Kinetic studies have established that cyanovinyl phosphate undergoes a slow pseudo-first-order hydrolysis in aqueous solution. Cyanovinyl phosphate converts uridine to uridine monophosphate and phosphate to pyrophosphate.

Entities: Chemical

Mesh：

Substances：

Year: 1968 PMID： 4297644 DOI： 10.1126/science.161.3836.53

Source DB: PubMed Journal: Science ISSN： 0036-8075 Impact factor: 47.728

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Cited

17 in total

1. Concentration by evaporation and the prebiotic synthesis of cytosine.

Authors: K E Nelson; M P Robertson; M Levy; S L Miller
Journal: Orig Life Evol Biosph Date: 2001-06 Impact factor: 1.950

2. Primary sources of phosphorus and phosphates in chemical evolution.

Authors: E Macia; M V Hernandez; J Oro
Journal: Orig Life Evol Biosph Date: 1997-12 Impact factor: 1.950

3. Adsorption of 5'-AMP and catalytic synthesis of 5'-ADP onto phosphate surfaces: correlation to solid matrix structures.

Authors: A C Tessis; H Salim De Amorim; M Farina; F DeSouza-Barros; A Vieyra
Journal: Orig Life Evol Biosph Date: 1995-08 Impact factor: 1.950

4. The investigation of the HCN derivative diiminosuccinonitrile as a prebiotic condensing agent. The formation of phosphate esters.

Authors: J P Ferris; H Yanagawa; P A Dudgeon; W J Hagan; T E Mallare
Journal: Orig Life Evol Biosph Date: 1984 Impact factor: 1.950

5. Quantum chemical study of relative reactivities of a series of amines and nitriles: relevance to prebiotic chemistry.

Authors: G H Loew; S Chang; D Berkowitz
Journal: J Mol Evol Date: 1975-07-11 Impact factor: 2.395

6. Pyrophosphate and adenosine 5'-diphosphate synthesis from phospho(enol)pyruvate: catalysis by phosphate minerals and modulation by dimethyl sulfoxide.

Authors: M Hermes-Lima; A C Tessis; G Costa Sarmento; A Vieyra
Journal: J Mol Evol Date: 1997-01 Impact factor: 2.395

Cyanovinyl phosphate: a prebiological phosphorylating agent?

1. Concentration by evaporation and the prebiotic synthesis of cytosine.

2. Primary sources of phosphorus and phosphates in chemical evolution.

3. Adsorption of 5'-AMP and catalytic synthesis of 5'-ADP onto phosphate surfaces: correlation to solid matrix structures.

4. The investigation of the HCN derivative diiminosuccinonitrile as a prebiotic condensing agent. The formation of phosphate esters.

5. Quantum chemical study of relative reactivities of a series of amines and nitriles: relevance to prebiotic chemistry.

6. Pyrophosphate and adenosine 5'-diphosphate synthesis from phospho(enol)pyruvate: catalysis by phosphate minerals and modulation by dimethyl sulfoxide.

Review 7. Chemical evolution. Recent syntheses of bioorganic molecules.

8. Chemical evolution. 18. Synthesis of pyrimidines from guanidine and cyanoacetaldehyde.

9. The prebiotic chemistry of nucleotides.

10. Nonenzymatic formation of "energy-rich" lactoyl and glyceroyl thioesters from glyceraldehyde and a thiol.