Literature DB >> 4094753

Limits on asymmetric orthopositronium formation in high Z optically active molecules.

J Van House, A Rich, P W Zitzewitz.   

Abstract

The proposed connection between the parity violating handedness of beta particles in radioactive decay and the sign (L) of biological chirality (the Vester-Ulbricht [V-U] hypothesis) is experimentally tested. The theoretically predicted asymmetry in triplet positronium formation (Aps) is measured in several high Z optically active molecules using low energy positrons with a net helicity. We find Aps less than 3 X 10(-4) in selenocystine (Z = 34) and thyroxine (Z = 53), excluding part of the theoretically predicted range of 4 X 10(-3) greater than Aps greater than 2 X 10(-6) in these molecules. The connection between these limits and limits on asymmetric radiolysis (AR) is made, with a new limit of AR greater than 10(-9) being placed. This limit on AR, which is thirty times lower than a previous measurement in the amino acid leucine (Z = 6), is still not small enough to rule out the V-U hypothesis. rule out the V-U hypothesis.

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Year:  1985        PMID: 4094753     DOI: 10.1007/BF01808051

Source DB:  PubMed          Journal:  Orig Life Evol Biosph        ISSN: 0169-6149            Impact factor:   1.950


  4 in total

1.  Beta decay and the origin of biological chirality: new experimental results.

Authors:  J Van House; A Rich; P W Zitzewitz
Journal:  Orig Life       Date:  1984

2.  beta Decay and the origins of biological chirality: experimental results.

Authors:  D W Gidley; A Rich; J Van House; P W Zitzewitz
Journal:  Nature       Date:  1982-06-24       Impact factor: 49.962

3.  beta Decay and the origins of biological chirality: theoretical results.

Authors:  R A Hegstrom
Journal:  Nature       Date:  1982-06-24       Impact factor: 49.962

4.  New estimates of asymmetric decomposition of racemic mixtures by natural beta-radiation sources.

Authors:  R A Hegstrom; A Rich; J Van House
Journal:  Nature       Date:  1985-01-31       Impact factor: 49.962

  4 in total
  1 in total

Review 1.  The origin and amplification of biomolecular chirality.

Authors:  W A Bonner
Journal:  Orig Life Evol Biosph       Date:  1991       Impact factor: 1.950

  1 in total

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