Literature DB >> 3927485

Stereostructure of the archaebacterial C40 diol.

C H Heathcock, B L Finkelstein, T Aoki, C D Poulter.   

Abstract

The stereostructure of the archaebacterial C40 diol has been established as (3R,7R,11R,15S,18S,22R,26R,30R)-3,7,11,15,18,22,26,30- octamethyldotriacontane-1,32-diol by stereorational total synthesis. This provides the final evidence necessary to establish the structure of an archaebacterial membrane substance that is a 72-membered-ring tetraether with 18 stereocenters.

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Year:  1985        PMID： 3927485     DOI： 10.1126/science.3927485

Source DB:  PubMed          Journal:  Science        ISSN： 0036-8075            Impact factor:   47.728


  5 in total

1.  Archaeal lipids and their biotechnological applications.

Authors:  A Gambacorta; A Gliozzi; M De Rosa
Journal:  World J Microbiol Biotechnol       Date:  1995-01       Impact factor: 3.312

2.  Isoprenoid biosynthesis: the evolution of two ancient and distinct pathways across genomes.

Authors:  B M Lange; T Rujan; W Martin; R Croteau
Journal:  Proc Natl Acad Sci U S A       Date:  2000-11-21       Impact factor: 11.205

3.  Total synthesis of geranylgeranylglyceryl phosphate enantiomers: substrates for characterization of 2,3-O-digeranylgeranylglyceryl phosphate synthase.

Authors:  Honglu Zhang; Kyohei Shibuya; Hisashi Hemmi; Tokuzo Nishino; Glenn D Prestwich
Journal:  Org Lett       Date:  2006-03-02       Impact factor: 6.005

4.  Identification of an Archaeal type II isopentenyl diphosphate isomerase in methanothermobacter thermautotrophicus.

Authors:  Sam J Barkley; Rita M Cornish; C Dale Poulter
Journal:  J Bacteriol       Date:  2004-03       Impact factor: 3.490

5.  Evolving biosynthetic tangos negotiate mechanistic landscapes.

Authors:  Michael B Austin; Paul E O'Maille; Joseph P Noel
Journal:  Nat Chem Biol       Date:  2008-04       Impact factor: 15.040
  5 in total

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