| Literature DB >> 3688435 |
P J Tarcha1, V P Chu, D Whittern.
Abstract
NMR and mass spectroscopic evidence has been obtained which indicates that the product of the oxidation of o-phenylenediamine by hydrogen peroxide, uncatalyzed or catalyzed by horseradish peroxidase, is 2,3-diaminophenazine. These results settle disparate literature descriptions. The process is most likely free radical in nature starting with the abstraction of a labile amino hydrogen atom.Entities:
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Year: 1987 PMID: 3688435 DOI: 10.1016/0003-2697(87)90224-7
Source DB: PubMed Journal: Anal Biochem ISSN: 0003-2697 Impact factor: 3.365