Literature DB >> 3588294

The reaction mechanism of N-benzoylimidazole with ribonucleotides.

Y Wang, X Y Liu, Z W Yang, Q W Wang, Y Z Xu, Q Z Wang, J F Xu.   

Abstract

The reaction of uridine 3'-phosphate with benzoylimidazole in the absence and presence of a strong base was followed up by 31P and 1H nmr as well as paper electrophoresis. Possible reaction courses were proposed, the reaction rate constants were calculated and the reaction mechanism was discussed. It is possible to selectively acylate ribonucleotides with benzoylimidazole by appropriate choice of the base used.

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Year:  1987        PMID: 3588294      PMCID: PMC340848          DOI: 10.1093/nar/15.10.4291

Source DB:  PubMed          Journal:  Nucleic Acids Res        ISSN: 0305-1048            Impact factor:   16.971


  5 in total

1.  The effect of substituents on the deacylation of benzoyl-chymotrypsins.

Authors:  M CAPLOW; W P JENCKS
Journal:  Biochemistry       Date:  1962-09       Impact factor: 3.162

2.  [Synthesis of dinucleotides in the ribose series with terminal 3'-phosphate groups].

Authors:  H J Rhaese; W Siehr; F Cramer
Journal:  Justus Liebigs Ann Chem       Date:  1967-04

3.  Studies on polynucleotides. LI. Syntheses of the 64 possible ribotrinucleotides derived from the four major ribomononucleotides.

Authors:  R Lohrmann; D Söll; H Hayatsu; E Ohtsuka; H G Khorana
Journal:  J Am Chem Soc       Date:  1966-02-20       Impact factor: 15.419

4.  Spectrophotometric determination of the pK values for dissociation of the sugar hydroxyls in pyrimidine arabinonucleosides.

Authors:  E Darzynkiewicz; H Sierakowski; D Shugar
Journal:  Z Naturforsch C Biosci       Date:  1975 Sep-Oct

5.  Some aspects of chemical synthesis of oligoribonucleotides.

Authors:  W Yu
Journal:  Nucleic Acids Symp Ser       Date:  1980
  5 in total

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