| Literature DB >> 3580534 |
A L Barra, J B Robert, L Wiesenfeld.
Abstract
The formula giving the parity-violating electroweak interaction contribution to the magnetic shielding tensor has been applied to enantiomers containing thallium. Using an extended Hückel relativistically parameterized method a chemical shift difference close to 1 mHz at 11.7 T is calculated in two couples of enantiomers. Such a difference is slightly lower than the extreme line width which may be actually reached in ultra-high resolution NMR.Mesh:
Year: 1987 PMID: 3580534 DOI: 10.1016/0303-2647(87)90020-7
Source DB: PubMed Journal: Biosystems ISSN: 0303-2647 Impact factor: 1.973