Surface functionalization of bamboo leave mediated synthesized SiO2 nanoparticles: Study of adsorption mechanism, isotherms and enhanced adsorption capacity for removal of Cr (VI) from aqueous solution.

Green synthesis of nanoparticles (NPs) provides economic and environmental benefits as an alternative to chemical or physical methods. Furthermore, the surface properties of such NPs can be modulated by means of the functionalization with different groups making them suitable for various advanced functional applications including water pollutants removal using adsorption technique. In the present work, an eco-friendly synthesis route for nano-adsorbent SiO2 NPs and subsequent surface modifications for enhanced adsorption capacity in removal of Cr(VI) ions from aqueous solution are reported. The green synthesis of SiO2 NPs was carried out using simple bamboo leaves followed by surface modification with amine (A-SiO2) and carboxylic (C-SiO2) functional groups with aim to study the effect of functionalization on adsorption capacity. These nano-adsorbents were characterized by FTIR, SEM, XPS, BET, and zeta potential. and adsorption of Cr(VI) was studied at varying parameters i.e. NPs mass, contact time, and solution pH. The investigation shows interesting results revealing the importance of interactions between the surface functional groups on SiO2 NPs and Cr(VI) species as well as experimental conditions for the choice of surface modifier to achieve a maximum adsorption capacity. The adsorption mechanism has been studied using Langmuir, Freundlich and Temkin adsorption isotherms. The maximum adsorption capacity has been achieved in the case of A-SiO2 NPs which was found to 174 mg/g and much higher than that of SiO2 and C-SiO2 NPs attributed to the selective adsorption and pH conditions. Additionally, A-SiO2 NPs exhibit excellent recyclability indicating their suitability for promising and long term potential applications. This study provides a novel, simple and cost-effective synthesis/surface engineering technology for producing high performance recyclable nano-adsorbents for adsorptive removal of Cr(VI).