Hydroxyapatite tailored hierarchical porous biochar composite immobilized Cd(II) and Pb(II) and mitigated their hazardous effects in contaminated water and soil.

A novel composite of hydroxyapatite tailored hierarchical porous biochar (HA-HPB) was synthesized and used for the adsorptive immobilization of Cd(II) and Pb(II) in water and soil. The hierarchical porous biochar (HPB) was prepared from rice husk through a molten-salt-assisted pyrolysis approach; then, a series of HA-HPB (with 0.5, 1, 2, 3, and 4 g of HPB) was prepared with co-precipitation procedure. All HA-HPBs, particularly HA-3HPB, revealed significantly higher removal efficiency of Cd(II) and Pb(II) (≥99.5%) in water than pristine biochar (5.79 - 24.12%). The immobilization efficiency of HA-3HPB for Cd(II) and Pb(II) was slightly inhibited by the ionic strength and co-existing cations. The Langmuir adsorption capacities of Cd(II) and Pb(II) were 88.1 and 110.2 mg/g, respectively. Ion exchange, complexation, cation-π interaction, and precipitation were the key mechanisms involved in the immobilization of Cd(II) and Pb(II) using HA-3HPB. The HA-3HPB reduced the availability of soil Cd (63.5 - 87.8%) and Pb (64.6 - 92.9%) compared to the unamended soil, and thus reduced their content in the Chinese cabbage shoots by 69.3 -95.4% for Cd and 66.5 -97.2% for Pb. These findings demonstrate the effectiveness of HA-HPB for remediation of Cd(II) and Pb(II) contaminated water and soil and mitigating the potential risks.