| Literature DB >> 35630132 |
Yuting Li1, Jingliang Bi2, Miao Tang1, Gui Lu1.
Abstract
The flow channel design of bipolar plates plays a significant role in the proton exchange membrane fuel cells operation, particularly in thermal and water management. The pursuit of low-pressure drop supply and flow field uniformity in PEM fuel cells has not stopped, resulting in numerous new bipolar plate flow channel designs. The biomimetic leaf vein shape-based flow channel and lung flow channel designs can significantly improve gas supply uniformity and reduce pressure drop. Therefore, we propose a snowflake-shaped bionic channel design by integrating the advantages of the leaf vein shape and lung shape channel. A 3D multi-physics fuel cell model is used to verify the feasibility and superiority of the bionic snowflake design in improving fuel cell performance, especially in reducing the pumping work. The local pressure distribution, oxygen distribution, water distribution, and current density distribution are used to reveal the enhancement mechanism of the new snowflake flow channel. The flow uniformity is further enhanced by using multi-objective (13 target parameters) and multi-parameter (18 independent variables) genetic algorithm optimization. The general goal of this work is to provide a new strategy for the thermal and water management of PEM fuel cells.Entities:
Keywords: PEM fuel cell; bionic flow field; flow channel; multi-objective genetic algorithm optimization
Year: 2022 PMID: 35630132 PMCID: PMC9144083 DOI: 10.3390/mi13050665
Source DB: PubMed Journal: Micromachines (Basel) ISSN: 2072-666X Impact factor: 3.523
Summary of flow channel design for PEM fuel cells.
| Year | Peak Power Density/w cm−2 | Pressure Drop/pa | Advantages | Disadvantages | Figure |
|---|---|---|---|---|---|
| 2010 | 0.276 | 212 | Small pressure drop. | The low channel flow rate results in low differential pressure across the battery. |
|
| 2010 | 0.45 | 3295 | The large pressure drop between adjacent flow channels leads to the additional benefits of sub-rib convection bypass, which is beneficial to drainage and diffusion is the main transport mechanism of a single serpentine channel. | The parasitic loss and the pressure difference between the cathode and the anode are large and the membrane may be damaged. Increasing the cell area may cause an excessive pressure drop in the flow field. |
|
| 2010 | 0.423 | 5688 | Despite its high water content, it does not affect battery performance. It is a promising form of the flow channel and convection under the ribs has proven to be very beneficial for battery performance. | Large pressure drop and uneven distribution. |
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| 2012 | 0.55 | 250 | Enhance the lateral transport phenomenon and increase the heat and mass transfer significantly. The inlet and outlet channels are adjacent and the pressure drop forces the reactant gas in the channel to flow through the gas diffusion layer and the catalyst layer and complementing the lack of reactants in the outlet channel. The outlet channel is smaller in size than the inlet, helping to remove moisture from the porous layer. | Around the circular area connecting the inlet and the outlet, especially where there is no flow channel, water will accumulate on the catalytic layer, reducing the contact area of the reaction. |
|
| 2013 | 0.207 | small | Widely used flow field configuration with the advantage of reduced pressure. | There are disadvantages of uneven flow distribution and stagnation zone. |
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| 2013 | 0.587 | N/A | Easy to manufacture, the shape of the channel takes into account the consumption of reactants. Speed distribution is uniform. Water management is good, management is good. |
| |
| 2012 | 1.1 | As the reactants approach the outlet, the cross-sectional area of the main channel decreases and increased pressure forces the species to flow laterally, which will allow the reactants to spread more evenly across the diffusion layer. | There are many reactants attached to the outlet wall; there may be insufficient reactants between the downstream ribs. |
| |
| 2014 | 0.57 | 6485 | Using Murray’s law to narrow the third branch, the mass fraction of oxygen and oxygen is more uniform. | The designed inlet and outlet channels are disconnected and a large pressure drop is expected, which means that there is forced convection in the channel. |
|
| 2015 | 0.302 | 29,900 | More uniform reactant concentration and velocity distribution. Higher consumption of reactants. Geometry crosses each other to enhance the drainage effect of sub-rib flow. In relatively small channels, surface tension, inertial and viscous forces dominate, while gravity is negligible. | The designed inlet and outlet channels are disconnected and a large pressure drop is expected, which means that there is forced convection in the channel. |
|
| 2017 | 0.088 | Good quality transportation ability, strong water management ability. | The overall effect is not ideal. |
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| 2017 | 0.088 | Good quality transportation ability, strong water management ability. | The overall effect is not ideal. |
| |
| 2018 | 0.54 | 2000 | The repeated branching and fractal structure ensure a uniform distribution of oxygen within a given volume. The pressure drop is the same for each branch. The self-similar structure of the lung remains thermodynamically optimal. | The complex manufacturing process has an excellent performance in low humidity conditions; in contrast, it is easy to accumulate water. |
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| 2019 | 0.83 | 5500 | Enhances lateral flow of reactants and replenishment of fresh oxygen. Enhance water management. Membrane with good water content and better proton conductivity. | Large pressure drop, there will still be poor water management downstream. |
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| 2015 | 0.44 | 4155 | Improved standard finger-fork shape, reduced pressure drop, better uniformity. | Large pressure drop, the poor overall effect. |
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| 2015 | 0.42 | 208 | Apply Murray’s Law to calculate branch width. | The reactants are unevenly distributed, the pressure drop is large, and the overall effect is worse than that of a single snake-type flow field. |
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| 2017 | 1.6 | Efficiently partition reactants and remove products with minimal flow loss. Low pump power and low humidity. | Lower current density results in more severe membrane dehydration, which reduces performance. |
| |
| 2017 | 0.99 | 3.17 | Suitable fluid flow rate, no dead point. Reduced production costs and production time. | Uneven fuel distribution and low fuel utilization. |
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Figure 1Snowflake bionic flow channel design.
Fuel cell parameters.
| Parameters | Value |
|---|---|
| Anode reference current density, A m−2 | 10,000 |
| Cathode reference current density, A m−2 | 20 |
| Anode reference concentration, kmol m−3 | 1.0 |
| Cathode reference concentration, kmol m−3 | 1.0 |
| Anode concentration exponent | 0.5 |
| Cathode concentration exponent | 1.0 |
| Anode exchange coefficient | 2 |
| Cathode exchange coefficient | 2 |
| Open-circuit voltage, V | 1.1 |
| Current collector effective conductivity, 1 (Ω·m)−1 | 1 × 106 |
| Diffusion layer porosity | 0.5 |
| Diffusion layer viscous resistance, 1 m−2 | 1 × 1012 |
| Diffusion layer effective conductivity, 1 (Ω·m)−1 | 5000 |
| Catalyst layer porosity | 0.5 |
| Diffusion layer viscous resistance, 1 m−2 | 1 × 1012 |
| Catalyst layer effective conductivity, 1 (Ω·m)−1 | 5000 |
| Catalyst layer specific surface area, 1 m−1 | 2 × 105 |
| Reference diffusivity, m2 s−1 | 3 × 10−5 |
| Membrane equivalent weight, kg kmol−1 | 1 100 |
| Membrane protonic conduction coefficient | 1.0 |
| Membrane protonic conduction exponent | 1.0 |
| Membrane effective conductivity, 1 (Ω·m)−1 | 1 × 10−16 |
Figure 2Model validation.
Figure 3The polarization curve and power density curve of PEM fuel cells with various designs: (a) U-I curve; (b) dual serpentine, leaf, and lung designs.
Figure 4Peak power density of PEM fuel cells with various flow channels.
The pressure drops for the PEM fuel cells.
| Voltage | Pressure Drop | |||
|---|---|---|---|---|
| (V) | Dual Serpentine | Leaf Shape | Lung Shape | Snowflake Shape |
| Range (pa) | Range (pa) | Range (pa) | Range (pa) | |
| 0.2 | 0.21–59.23 | 8.59–17.65 | 1.41–14.11 | 0.09–1.14 |
| 0.3 | 0.21–59.49 | 8.06–16.55 | 1.40–13.80 | 0.09–1.15 |
| 0.4 | 0.21–59.56 | 8.64–17.34 | 1.40–14.17 | 0.09–1.16 |
| 0.5 | 0.22–60.02 | 8.37–17.00 | 1.37–10.82 | 0.09–1.09 |
| 0.6 | 0.22–59.81 | 8.30–16.83 | 1.30–9.80 | 0.09–1.17 |
| 0.7 | 0.23–59.91 | 8.19–16.57 | 1.27–9.66 | 0.09–1.16 |
| 0.8 | 0.22–58.44 | 7.81–16.08 | 1.25–5.55 | 0.08–1.10 |
| 0.9 | 0.22–54.82 | 7.78–15.88 | 1.21–1.59 | 0.08–1.06 |
| 1.0 | 0.22–54.28 | 7.85–15.97 | 4.77–7.16 | 0.08–1.04 |
Figure 5Oxygen mass fraction in the flow channel (0.8 V): (a) Snowflake bionic flow channel; (b) dual serpentine flow channel; (c) leaf-shape bionic flow channel; (d) lung-shape bionic flow channel.
Figure 6Oxygen mass fraction of cathode gas diffusion layer (0.8 V): (a) Snowflake bionic flow channel; (b) dual serpentine flow channel; (c) leaf-shape bionic flow channel; (d) lung-shape bionic flow channel.
Figure 7Water mass fraction in cathode channel (0.8 V): (a) Snowflake bionic flow channel; (b) dual serpentine flow channel; (c) leaf-shape bionic flow channel; (d) lung-shape bionic flow channel.
Figure 8Water mass fraction in cathode diffusion layer (0.8 V): (a) Snowflake bionic flow channel; (b) dual serpentine flow channel; (c) leaf-shape bionic flow channel; (d) lung-shape bionic flow channel.
Figure 9The current density distribution of the membrane (A m−2) (0.8 V): (a) Snowflake bionic flow channel; (b) dual serpentine flow channel; (c) leaf-shape bionic flow channel; (d) lung-shape bionic flow channel.
Figure 10Flow diagram of MOGA optimization for the snowflake flow channel fuel cells.
Figure 11The MOGA optimization for snowflake flow channel fuel cell: (a) initial design parameters; (b) optimized parameters.
Multi-objective genetic algorithm parameters.
| Input | Output | ||||
|---|---|---|---|---|---|
| Before Optimization | After Optimization | Before Optimization | After Optimization | ||
| P1 | 4.5 mm | 4.1128 | P19 main | 1.257 × 10−7 | 1.1706 × 10−7 |
| P2 | 4.5 mm | 4.3572 | P20 branch | 1.0541 × 10−7 | 9.8605 × 10−8 |
| P3 | 4.5 mm | 5.1785 | P21 branch | 1.0624 × 10−7 | 1.1115 × 10−7 |
| P4 | 4.5 mm | 5.2118 | P22 main | 8.9896 × 10−8 | 1.0124 × 10−7 |
| P5 | 4.5 mm | 5.2723 | P23 branch | 1.6012 × 10−7 | 1.6043 × 10−7 |
| P6 | 4.5 mm | 5.293 | P24 main | 9.105 × 10−7 | 1.0011 × 10−7 |
| P7 | 4.5 mm | 4.5752 | P25 main | 1.2435 × 10−7 | 1.0865 × 10−7 |
| P8 | 4.5 mm | 5.2457 | P26 branch | 1.0516 × 10−7 | 1.1415 × 10−7 |
| P9 | 4.5 mm | 3.7166 | P27 branch | 1.513 × 10−7 | 9.6089 × 10−8 |
| P10 | 4.5 mm | 5.2221 | P28 main | 8.8445 × 10−8 | 9.4439 × 10−8 |
| P11 | 4.5 mm | 5.2697 | p29 branch | 1.5974 × 10−7 | 1.5435 × 10−7 |
| P12 | 4.5 mm | 3.8161 | P30 main | 8.9976 × 10−7 | 9.4862 × 10−8 |
| P13 | 4.5 mm | 5.1571 | P31deviation | 2.1188 × 10−14 | 1.4835 × 10−14 |
| P14 | 4.5 mm | 4.2994 | |||
| P15 | 4.5 mm | 3.7291 | |||
| P16 | 4.5 mm | 3.819 | |||
| P17 | 4.5 mm | 5.2364 | |||
| P18 | 4.5 mm | 4.7414 |