Literature DB >> 35590512

Inverse Vulcanization of Elemental Sulfur to Prepare Polymeric Electrode Materials for Li-S Batteries.

Adam G Simmonds1, Jared J Griebel1, Jungjin Park2, Kwi Ryong Kim2, Woo Jin Chung1, Vladimir P Oleshko3, Jenny Kim3, Eui Tae Kim2, Richard S Glass1, Christopher L Soles3, Yung-Eun Sung2, Kookheon Char2, Jeffrey Pyun1,2.   

Abstract

Sulfur-rich copolymers based on poly(sulfur-random-1,3-diisopropenylbenzene) (poly(S-r-DIB)) were synthesized via inverse vulcanization to create cathode materials for lithium-sulfur battery applications. These materials exhibit enhanced capacity retention (1005 mAh/g at 100 cycles) and battery lifetimes over 500 cycles at a C/10 rate. These poly(S-r-DIB) copolymers represent a new class of polymeric electrode materials that exhibit one of the highest charge capacities reported, particularly after extended charge-discharge cycling in Li-S batteries.

Entities:  

Year:  2014        PMID: 35590512     DOI: 10.1021/mz400649w

Source DB:  PubMed          Journal:  ACS Macro Lett        ISSN: 2161-1653            Impact factor:   6.903


  2 in total

1.  Sustainable inverse-vulcanised sulfur polymers.

Authors:  Douglas J Parker; Samantha T Chong; Tom Hasell
Journal:  RSC Adv       Date:  2018-08-06       Impact factor: 4.036

2.  On the Structure of Sulfur/1,3-Diisopropenylbenzene Co-Polymer Cathodes for Li-S Batteries: Insights from Density-Functional Theory Calculations.

Authors:  Rana Kiani; Daniel Sebastiani; Pouya Partovi-Azar
Journal:  Chemphyschem       Date:  2021-10-22       Impact factor: 3.520

  2 in total

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