Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Chirality-driven self-assembly: application toward renewable/exchangeable resin-immobilized catalysts.

Literature DB >> 35583170

Chirality-driven self-assembly: application toward renewable/exchangeable resin-immobilized catalysts.

Elizabeth M Menuey¹, John Zhou¹, Shuyuan Tian¹, Reid E Brenner¹, Zhaoyang Ren², Duy H Hua², Kathleen V Kilway¹, Shin A Moteki¹.

Abstract

Resin-immobilized catalysts were prepared through chirality-driven self-assembly. The method allows the resin-immobilized catalyst to be regenerated under mild conditions and in situ catalyst exchange to be carried out quantitatively. The uniqueness of the methodology was demonstrated by the preparation of a catalyst for TEMPO oxidation as well as a two-step sequential TEMPO oxidation/aldol condensation sequence enabled by facile catalyst exchange.

Entities: Chemical

Mesh：

Year: 2022 PMID： 35583170 PMCID： PMC9341390 DOI： 10.1039/d2ob00439a

Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.890

Keyword Cloud
References

48 in total

1. Preparation of polymer-supported ligands and metal complexes for use in catalysis.

Authors: Nicholas E Leadbeater; Maria Marco
Journal: Chem Rev Date: 2002-10 Impact factor: 60.622

2. Direct organocatalytic aldol reactions in buffered aqueous media.

Authors: Armando Córdova; Wolfgang Notz; Carlos F Barbas
Journal: Chem Commun (Camb) Date: 2002-12-21 Impact factor: 6.222

3. Asymmetric catalysis using self-assembled chiral bidentate P,P-ligands.

Authors: James M Takacs; D Sahadeva Reddy; Shin A Moteki; Di Wu; Hector Palencia
Journal: J Am Chem Soc Date: 2004-04-14 Impact factor: 15.419

Review 4. Asymmetric heterogeneous catalysis.

Authors: Maja Heitbaum; Frank Glorius; Iris Escher
Journal: Angew Chem Int Ed Engl Date: 2006-07-17 Impact factor: 15.336

9. Rapid fluorescent screening for bifunctional amine-acid catalysts: efficient syntheses of quaternary carbon-containing aldols under organocatalysis.

Authors: Nobuyuki Mase; Fujie Tanaka; Carlos F Barbas
Journal: Org Lett Date: 2003-11-13 Impact factor: 6.005

Review 10. Supramolecular Strategies for the Recycling of Homogeneous Catalysts.

Authors: Bo Zhang; Joost N H Reek
Journal: Chem Asian J Date: 2021-10-22

Chirality-driven self-assembly: application toward renewable/exchangeable resin-immobilized catalysts.

1. Preparation of polymer-supported ligands and metal complexes for use in catalysis.

2. Direct organocatalytic aldol reactions in buffered aqueous media.

3. Asymmetric catalysis using self-assembled chiral bidentate P,P-ligands.

Review 4. Asymmetric heterogeneous catalysis.

5. Organic polymer supports for synthesis and for reagent and catalyst immobilization.

6. Permeable Self-Assembled Molecular Containers for Catalyst Isolation Enabling Two-Step Cascade Reactions.

Review 7. Fundamentals of green chemistry: efficiency in reaction design.

8. Synthesis of dendritic catalysts and application in asymmetric transfer hydrogenation.

9. Rapid fluorescent screening for bifunctional amine-acid catalysts: efficient syntheses of quaternary carbon-containing aldols under organocatalysis.

Review 10. Supramolecular Strategies for the Recycling of Homogeneous Catalysts.