| Literature DB >> 35566816 |
Adrian Benitez Lozano1,2, Santiago Henao Álvarez1, Carlos Vargas Isaza1, Wilfredo Montealegre-Rubio2.
Abstract
The currently growing demand for metallic and polymeric products has undoubtedly changed the rules of manufacturing, enabling customers to more functionally define their products based on their needs. Nowadays, a new technique for rapid tooling, Additive Manufacturing (AM), can create customized products with more complex geometries and short life cycles (flexibility) in order to keep up with the new variables imposed by the manufacturing environment. In the last two decades, the migration from subtractive manufacturing to AM has materialized such products with reduced costs and cycle times. AM has been recently promoted to develop polymer molds for product manufacturing. This paper reviews the main findings in the literature concerning polymer molds created by AM compared to conventional (metal) molds obtained by subtractive manufacturing. Information about specific topics is scarce or nonexistent, for example, about the characterization of the most commonly injected materials and molds used in this type of technology, their mechanical properties (part and mold), designs for all types of geometries, and costs. These aspects are addressed in this literature review, highlighting the advantages of this alternative manufacturing process, which is considered a desirable technology worldwide.Entities:
Keywords: injection molding; mold additive manufacturing; mold characterization; polymer molds; rapid tooling; subtractive manufacturing
Year: 2022 PMID: 35566816 PMCID: PMC9105666 DOI: 10.3390/polym14091646
Source DB: PubMed Journal: Polymers (Basel) ISSN: 2073-4360 Impact factor: 4.329
Figure 1Chronology of the most common subtractive and additive manufacturing techniques for polymer/metal molds.
Figure 2Network of countries based on co-authorship.
Figure 3Network of keywords retrieved from the literature search.
Search results obtained with each string.
| TITLE-ABS-KEY | Number of Retrieved Documents and Related References | ||
|---|---|---|---|
| Without Filter | Filter | References | |
| “Additive manufacturing” AND “Rapid tooling” OR “Polymer Mould” | 81 | 26 | [ |
| “Rapid tooling” AND “Additive manufacturing | 83 | 11 | [ |
| “Additive manufacturing” AND “Rapid tooling” AND “Injection molding” AND “Failure” | 46 | 31 | [ |
| “Additive manufacturing” AND “Rapid tooling” AND “Injection molding” AND “Design” | 15 | 12 | [ |
| Filter: Review of the abstract and relationship with the search string | |||
Figure 4(a) Pressure field and temperatures in a refrigeration system. (b) Cooling system by means of baffles.
Figure 5Solid models of cavity insert and cores (a) without cooling channels, (b) with conventional cooling channels, (c) with parallel conformal cooling channels, and (d) with series conformal cooling channels.
Technical guide to design mold cavities based on recent studies in the field [40,43,44,45,46].
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| Draft | Use angles of approximately 3–5 degrees for the vertical wall. This will reduce mold damage, and the formed parts are less likely to resist ejection from the mold. |
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| Parting surfaces | Make sure that parting surfaces have minimal flash. For this purpose, try to efficiently adjust the clamping force to compress the plastic material. Check injection parameters such as injection rate, temperature, and pressure. |
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| Core pins | Use core pins with an aspect ratio of 3:1 (height: width). Core pins could deflect due to the pressure in the filling process. A 3D printed insert can be designed to improve mold longevity. |
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| Holes | Use holes with diameters larger than 0.8 mm. Smaller holes could be machined prior to mold assembly. | |
| Shrinkage compensation | It is important to know the contraction or expansion of the printed material, generally in percentages. Based on these data, scale the core and the cavity to compensate for the shrinkage of the resin that occurs with conventional injection molding. | |
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| Gates | Enlarge the gates depending on the viscosity of the plastic material used for the part and the mold’s flow characteristics. Use or design gates three times larger than those used in metal molds. Make edge gate thickness equal to the wall thickness of the part at the point of injection. These measures will improve material flow and decrease pressure within the tool. |
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| Runners | Hot runner systems are not recommended. If they are used, they do not require adjustment. |
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| Sprue | Use a sprue bushing with a minimum draft angle of 3 degrees. If a bushing is used, undersize the hole by 0.2–0.3 mm before printing and ream to size during mold assembly. Avoid physical or direct contact between the molding machine’s nozzle and the mold insert. |
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| Ejection system | If an ejection system is used, add ejector holes as needed. As with the sprue bushing, undersize the holes by 0.2–0.3 mm (0.008–0.012 in) and ream to size during mold assembly. It is recommended to make sure the holes for the ejector pins will not be too close to the edges. It will weaken the mold especially after reaming. | |
| Cooling system | Cooling systems will not significantly affect molding cycle times or part quality thanks to the thermal characteristics of PolyJet molds. However, a cooling system can improve tool life; on average, a 20% improvement can be expected. The improvement increases as the depth of the cavity and height of the core decreases since the cooling effects reach more of the surface area of the molding cavity. In recent studies [ | |
Figure 6Ishikawa diagram of different sources of crack initiation and catastrophic failure in polymer RTIM.
Summary of studies that have evaluated different polymer RTIM processes.
| Mold Material | Additive Technique or Machining | Method Used to Evaluate Mold Performance | Injected Polymer | Results (Mold/Part) | Ref. |
|---|---|---|---|---|---|
| Aremco 805 epoxy | FDM | Accuracy of injected parts | Polyamide | The dimensional error of the injection-molded part is less than 3%, and the warpage is almost 1 mm across the length of the component. | [ |
| Acrylate-based photopolymer | Digital Light Processing (DLP) | Mold failure (# of shots vs. failure) | Liquid silicone rubber | Small-sized parts for drug-releasing (micro)implants were manufactured using micro injection molding. Molds manufactured by DLP did not suffer significant wear when they were used for a low number of microinjection molding cycles (n ~ 8). | [ |
| Digital ABS, aluminum | PolyJet | Characterization of molded parts | Isotactic polypropylene | Injected parts showed slower cooling rates in Digital ABS inserts. Parts molded using aluminum tooling did not show a crystal structure. Additionally, parts molded on the digital ABS inserts exhibited higher shrinkage than those molded using aluminum tooling. The change in morphology and the presence of voids significantly affected the tensile behavior of the parts molded in Digital ABS, which broke with little cold drawing and exhibited higher tensile module a higher yield strength. | [ |
| PEI (Polyetherimide) | FDM | Thermal performance (specific heat capacity, i.e., Cp, and glass transition temperature); mechanical performance (Young’s modulus, loss factor, and compression tests); structural simulation | Polypropylene, POM | The PEI resulted thermally stable but not suitable for injection molding production of polypropylene parts due to prolonged cooling times and the elastic deformations of the inserts. Regarding the POM parts, the polymer insert did not present relevant damage. However, some problems occurred: difficult de-molding of the POM parts and water permeation through the inserts when the cooling system is active. | [ |
| Photopolymer Rigur (RGD450) | PolyJet | Mold failure (# of shots vs. failure) and accuracy of injected parts | Polypropylene | Between 94 to 122 parts (with some geometrical parameters such as undercuts) were injected. | [ |
| ABS and nylon (coated with copper) | FDM | Stainless steel powder combined with polypropylene as binder (metal injection molding, MIM) | The heat dissipation of the polymer mold was low compared to that of the metal mold. Therefore, the MIM part needs a longer cooling time inside the mold before ejection. | [ | |
| Epoxy Biresin, aluminum powder, SL resin, short steel fibers, and tool steel | Mold inserts manufactured by vacuum epoxy casting and stereolithography | Experimental data (pressure, temperature, ejection forces); computer simulation of injection molding (pressure, mold temperature); structural simulation | Polypropylene homopolymer | Molds made by stereolithography are viable if mold temperatures are controlled at 15 °C above the glass transition of the mold material. Otherwise, they exhibit premature failure, and their useful life is not enough for injection molds. The authors estimated the pressure associated with the high shrinkage of the injected polymer on the pins in the mold, which should be taken it into account to avoid failures in these elements. | [ |
| Epoxy-acrylate | PolyJet | Experimental data (cavity pressure, strain–time diagram) | Polypropylene homopolymer | The authors implemented on-line monitoring of the cavity pressure during the injection process, and they determined its effect on the deformation of the polymeric inserts by finding a direct relationship between these two variables. | [ |
| Different liquid photoresins | SLA 3D printing | Mechanical performance (flexural modulus); thermal performance (heating rate, maximum temperature, heat deflection temperature); cavity dimensions; experimental data (pressure, temperature) | LDPE | It was found that flexural modulus and elongation (two mechanical properties) are more relevant than deflection temperature under load to evaluate the performance of polymer molds made by additive SLA. The latter is useful to produce mold designs that require several changes in shape and dimensions. | [ |
| Methacrylic photopolymer | Vat photopolymerisation | Accelerated thermal ageing (weight loss of insert); mold failure (# of shots vs. failure); and mold surface features (average roughness) | - | The application of accelerated thermal aging to polymer mold inserts is a test to evaluate and predict their behavior when they are subjected to thermal loads that determine cyclic stresses. It was found that the stresses induced by the thermal loads of the injection molding process can be reduced by increasing cooling time; however, this produces longer cycle times, thus reducing productivity. | [ |
| Ceramic-filled epoxy composite, steel, and aluminum | SLA (polymeric composite) | CAE software (mold temperature); mold failure (# of shots vs. failure); mechanical performance (Young’s modulus, tensile strength, elongation); fiber characterization of polymeric composite | Polypropylene | The reinforced polymer mold withstood the injection of more than 100 parts before failure. The injected parts made of long-fiber reinforced polypropylene showed good mechanical properties and good dimensional accuracy. | [ |
| Digital ABS | - | Mold failure (# of shots vs. failure); thermal properties (heat capacity, heat deflection temperature, thermal expansion); CAE software (shear rate, shear stress, mold temperature) | ABS | Failure in the polymer mold was produced by a concentration of high temperatures, especially in the areas of the injection point and the mold cavity because higher shear rates and shear stresses were generated during mold filling. In polymeric molds, the solidified layer in the injected polymer is smaller than in typical steel molds, which indicates a more even cooling of the injected polymer through the flow path. | [ |
| Digital ABS, polyamide (PA) 3200 GF, and aluminum | PolyJet, selective laser sintering (SLS), and milling | Surface roughness | Copolymer polypropylene | The parts injected using RTIM showed a lower percentage of elongation compared to those injected in aluminum molds. This is explained by the lower thermal conductivity and higher roughness of the cavities in polymer RTIM. | [ |
| Epoxy-based resins | PolyJet | Experimental data (mold temperature distribution, mold temperature vs. time) and mechanical performance (storage modulus, loss factor) | Polypropylene and polylactic acid (PLA) | A comparative evaluation of three types of polymer mold inserts (i.e., without cooling channels, with conventional cooling channels, and with conformal cooling channels) determined that there was no difference in cooling efficiency between the insert without channels and that with conventional channels. The mold insert manufactured with conformal channels reduced the thermal load cycle by up to 70%, with good mold temperature control with respect to the glass transition temperature of the mold material. | [ |
| Ceramic photopolymer composite | Vat photopolymerization | Dimensional accuracy (dimensions over 10,000 shots) of mold and part | - | The diameters of the cylindrical elements in the mold were much smaller than the nominal diameters, which was due to the curing process of the photopolymer at the corners and edges after the printing process. The right angles of the corners did not undergo very significant changes in a range from 500 to 1000 injections. | [ |
| Digital ABS | PolyJet | Mold failure (# of shots vs. failure); CAE software (injection pressure, injection speed, shot volume, confidence of fill, ejection time, cooling time) | Polycarbonate | Reducing mold temperature and increasing melt temperature were the most important changes to delay failure in polymer rapid tooling inserts. | [ |
| Form 2 high temp. resin | Stereolithography, PolyJet | Mold failure (# of shots vs. failure) | Polystyrene | Using a hybrid mold (Master Unit Dye + AM inserts), it was possible to produce up to eighty components using both SLA and PolyJet printed molds. | [ |
| Digital ABS, RGD450, Accura Bluestone, Accura SL5530, Accura Xtreme, High Temp, Tough, PerForm, CE221, PA 3200 GF, and steel | PolyJet, stereolithography, CLIP, selective laser sintering, and milling | Mold failure (# of shots vs. failure) | Polypropylene, PA6, and PA6+GF30% | Two polymer reference materials, i.e., PerFrom and PA 3200 GF, offer a great technological advantage to make injection molds because all the polymers under evaluation could be injected without experiencing complete failure of the insert. They can even be used to inject high melting polymer materials. | [ |
| Though resin (THO), High Temperature (HT) resins, polyamide 12 filled with 50% of aluminum (PA50Al), and photopolymerization resin (ABS-like) | Stereolithography, laser sintering, and resin photo-polymerization (3D-PolyJet) | Mechanical performance (tensile strength, Charpy impact, flexural strength) and mold failure (# of shots vs. failure) | Elastomeric polyethylene, polypropylene, and ABS | Three mold materials obtained the highest elasticity and flexural modulus: HT, PA50Al, and ABS resin. They are the most appropriate materials to manufacture polypropylene injected prototypes. However, in the injection tests, the prototype mold made of ABS was only able to resist 12 injections before it began to crack. | [ |
| Acrylic-based photopolymer | PolyJet | Accuracy of injected parts; thermal properties (specific heat) | High density polyethylene | The injected parts showed large shrinkages. The mold printing material indicates that the glass transition temperature is located at 55 °C. | [ |
| VisiJet FTX Green | Stereolithography | Mold failure | Polypropylene | The failure of the insert mold was due to flexural stresses exerted by melt flow on the face of features perpendicular to flow front. Longer cycle times increase the ejection forces that may damage the tool. | [ |
| 420 stainless steel, bronze alloy, and ABS-like photopolymer | Milling, DMLS, and PolyJet | Thermal properties (specific heat); surface features (average roughness); mold failure (# of shots vs. failure); CAE software (mold temperature, deformation, stress); experimental data (mold temperature); cavity dimensions (average dimensions); mechanical performance (tensile strength) | Polypropylene | Regarding inserts of PolyJet molds, the coefficient of thermal expansion and compressibility of the polymeric insert material should be taken into account to calculate the nominal measurement of the injected part. Additionally, during ejection, ejection force, demolding angle, and cavity surface roughness should be reduced to facilitate ejections with minimal part-to-cavity interference and avoid polymer mold failure. | [ |
| Digital ABS, SAE 1045 steel, and Zamak 8 | PolyJet and milling | Surface features (average roughness); mold failure (# of shots vs. failure); cavity dimensions (average dimensions) | Polypropylene | The polymer injected in the ABS mold showed a slight increase in tensile strength and elastic modulus, and its impact resistance was increased by more than 30% compared to the parts injected in steel and Zamak. The crystallinity results of the injected polypropylene were not consistent with the cooling rate offered by the ABS mold because said polypropylene showed a lower degree of crystallinity than the parts injected in steel and Zamak. | [ |
| Formlabs White Resin, PolyJet Objet RGD515, and PEEK | Stereolithography (SLA), PolyJet, and Fused Deposition Modelling | Accuracy of injected parts | Polylactic acid (PLA) | The molds manufactured by stereolithography and PolyJet produced better finishes on the injected parts, while the mold made of PEEK by molten filament manufacturing presented delamination. In the SLA and PolyJet molds, the accuracy of the injected parts exhibited an average variation of less than 5%. | [ |
| Digital ABS, aluminum, and Very High Molecular Weight Polyethylene | PolyJet, milling | Finished mold roughness; finished mold profiles | Cyclic olefin copolymer; polypropylene | The surface finish of 3D printed molds can be improved by applying coatings on the mold surface to inject optical components. | [ |
| Photopolymer R11, steel, and aluminum | Stereolithography and milling | Thermal properties (heat capacity); mechanical performance (storage modulus, dimensional change); cavity dimensions (average dimensions); mold failure (# of shots vs. failure) | Polystyrene | The cooling time of polymer rapid tooling inserts is longer than that applied to aluminum and steel inserts due to their higher heat capacity compared to metal inserts. | [ |
Figure 7Cost curves of IM, AM for production, and AM for tooling.
Summary of studies into cost models of AM as a disruptive and complementary to IM.
| Related Studies | Cost Approach | AM Techniques | Year | |
|---|---|---|---|---|
| Disruptive | Synergy between AM and IM | |||
| [ | X | FDM, SLS, SLA | 2003 | |
| [ | X | SLS | 2006–2007 | |
| [ | X | SLS | 2012 | |
| [ | X | DLP | 2017 | |
| [ | X | X | FDM, POLYJET, SLA, SLS | 2017 |
| [ | X | FDM | 2017 | |
| [ | X | DLP | 2019 | |
| [ | X | POLYJET | 2020 | |