Self-Healing Metallacycle-Cored Supramolecular Polymers Based on a Metal-Salen Complex Constructed by Orthogonal Metal Coordination and Host-Guest Interaction with Amino Acid Sensing.

A platinum(II) metallacycle-cored supramolecular network based on a metal-salen complex was successfully constructed by two orthogonal noncovalent interactions (host-guest interactions and metal coordination interactions). The obtained metallo-supramolecular polymer could further form gels when the concentration of metallacycle 1 was 160.0 mM. This gel exhibited multiple stimuli-responsive gel-sol phase transitions under different stimuli, such as temperature, competitive guests, etc. Moreover, it exhibited good self-healing properties and could be used as a turn-off sensor for thiol-containing amino acids.