Literature DB >> 35357838

Visible-Light Enabled C(sp3)-C(sp2) Cross-Electrophile Coupling via Synergistic Halogen-Atom Transfer (XAT) and Nickel Catalysis.

Girish Suresh Yedase1, Avishek Kumar Jha1, Veera Reddy Yatham1.   

Abstract

We herein report the first visible-light-mediated cross-coupling of unactivated alkyl iodides with aryl bromides through synergistic halogen atom transfer (XAT) and nickel catalysis. This simple protocol operates under mild reaction conditions and tolerates a variety of functional groups affording C(sp3)-C(sp2) cross-coupling products in good to moderate yields.

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Year:  2022        PMID： 35357838     DOI： 10.1021/acs.joc.2c00251

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  The Merger of Benzophenone HAT Photocatalysis and Silyl Radical-Induced XAT Enables Both Nickel-Catalyzed Cross-Electrophile Coupling and 1,2-Dicarbofunctionalization of Olefins.

Authors:  Alberto Luridiana; Daniele Mazzarella; Luca Capaldo; Juan A Rincón; Pablo García-Losada; Carlos Mateos; Michael O Frederick; Manuel Nuño; Wybren Jan Buma; Timothy Noël
Journal:  ACS Catal       Date:  2022-09-01       Impact factor: 13.700

2.  α-Amino Radical Halogen Atom Transfer Agents for Metallaphotoredox-Catalyzed Cross-Electrophile Couplings of Distinct Organic Halides.

Authors:  Xianhai Tian; Jaspreet Kaur; Shahboz Yakubov; Joshua P Barham
Journal:  ChemSusChem       Date:  2022-06-13       Impact factor: 9.140
  2 in total

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