| Literature DB >> 35322841 |
D Christopher Braddock1, Natnicha Limpaitoon1, Krzysztof Oliwa1, Daniel O'Reilly1, Henry S Rzepa1, Andrew J P White1.
Abstract
The experimentally determined stereochemical outcome of an unprecedented hydride transfer from a lithium alkoxide to an aldehyde is reported, as deconvoluted by the combined use of a single enantiomer alkoxide in conjunction with a deuterium label. The stereoselective outcome is consistent with a computationally predicted transition state model stabilised by contributions from attractive dispersion forces.Entities:
Mesh：
Year: 2022 PMID： 35322841 DOI： 10.1039/d2cc01136k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222