Literature DB >> 35318548

The Stability of Unsubstituted BOPHY in Various Media.

Erol Tunca1, Efdal Teknikel2.   

Abstract

In this communication, we report our findings on the stability of unsubstituted BOPHY in different media. Our studies showed that unsubstituted BOPHY is highly unstable in water, methanol, and DMSO. The dye was observed to be stable in aprotic and/or relatively apolar solvents (ACN, acetone, DCM, and toluene) for a routine application. The pH of the medium was shown to affect the stability of the dye dramatically. Herein, we also presented a one-pot procedure for the synthesis of the dye.
© 2022. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.

Entities:  

Keywords:  Aqueous solution; BOPHY; Chemical stability; Fluorophore stability; One-pot synthesis

Mesh：

Substances：

Year:  2022        PMID： 35318548     DOI： 10.1007/s10895-022-02901-w

Source DB:  PubMed          Journal:  J Fluoresc        ISSN： 1053-0509            Impact factor:   2.217


  13 in total

1.  Polybrominated BOPHY Dyes: Synthesis, Reactivity, and Properties.

Authors:  Xiaokang Lv; Tingting Li; Qinghua Wu; Changjiang Yu; Lijuan Jiao; Erhong Hao
Journal:  J Org Chem       Date:  2018-01-24       Impact factor: 4.354

2.  Highly fluorescent BF2 complexes of hydrazine-Schiff base linked bispyrrole.

Authors:  Changjiang Yu; Lijuan Jiao; Ping Zhang; Zeya Feng; Chi Cheng; Yun Wei; Xiaolong Mu; Erhong Hao
Journal:  Org Lett       Date:  2014-05-21       Impact factor: 6.005

3.  BODIPY dyes and their derivatives: syntheses and spectroscopic properties.

Authors:  Aurore Loudet; Kevin Burgess
Journal:  Chem Rev       Date:  2007-10-09       Impact factor: 60.622

Review 4.  Fluorescent indicators based on BODIPY.

Authors:  Noël Boens; Volker Leen; Wim Dehaen
Journal:  Chem Soc Rev       Date:  2011-07-28       Impact factor: 54.564

5.  Synthesis of Highly Functionalized BOPHY Chromophores Displaying Large Stokes Shifts.

Authors:  Quentin Huaulmé; Antoine Mirloup; Pascal Retailleau; Raymond Ziessel
Journal:  Org Lett       Date:  2015-04-21       Impact factor: 6.005

6.  A new highly fluorescent and symmetric pyrrole-BF2 chromophore: BOPHY.

Authors:  Ingrid-Suzy Tamgho; Abed Hasheminasab; James T Engle; Victor N Nemykin; Christopher J Ziegler
Journal:  J Am Chem Soc       Date:  2014-04-07       Impact factor: 15.419

7.  Aromatic Ring Fused BOPHYs as Stable Red Fluorescent Dyes.

Authors:  Jun Wang; Qinghua Wu; Changjiang Yu; Yun Wei; Xiaolong Mu; Erhong Hao; Lijuan Jiao
Journal:  J Org Chem       Date:  2016-11-04       Impact factor: 4.354

8.  Testing the Limits of the BOPHY Platform: Preparation, Characterization, and Theoretical Modeling of BOPHYs and Organometallic BOPHYs with Electron-Withdrawing Groups at β-Pyrrolic and Bridging Positions.

Authors:  Yuriy V Zatsikha; Dion B Nemez; Rebecca L Davis; Simarpreet Singh; David E Herbert; Alex J King; Christopher J Ziegler; Victor N Nemykin
Journal:  Chemistry       Date:  2017-08-10       Impact factor: 5.236

9.  β-Furan-Fused bis(Difluoroboron)-1,2-bis((1H-pyrrol-2-yl)methylene)hydrazine Fluorescent Dyes in the Visible Deep-Red Region.

Authors:  Lin Zhou; Defang Xu; Huaizhi Gao; Chao Zhang; Fangfang Ni; Wenqi Zhao; Dandan Cheng; Xingliang Liu; Aixia Han
Journal:  J Org Chem       Date:  2016-08-05       Impact factor: 4.354

10.  Unusually Strong Long-Distance Metal-Metal Coupling in Bis(ferrocene)-Containing BOPHY: An Introduction to Organometallic BOPHYs.

Authors:  Hannah M Rhoda; Kullapa Chanawanno; Alexander J King; Yuriy V Zatsikha; Christopher J Ziegler; Victor N Nemykin
Journal:  Chemistry       Date:  2015-10-26       Impact factor: 5.236
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