Study on visible light photocatalytic performance of MIL-100(Fe) modified by carbon nanodots.

The emerging porous material metal organic framework (MOFs) has caught researchers' attention in the field of photocatalysis. In this study, a visible light-driven carbon nanodots/MIL-100(Fe) photocatalytic material was prepared by in situ synthesis method. The study found that the composite material loaded with 2.5 mg C-dots (2.5-carbon nanodots/MIL-100(Fe)) showed the best tetracycline degradation efficiency with 4.2 times higher than that of MIL-100(Fe) materials in a neutral environment. The superiority of 2.5-carbon nanodots/MIL-100(Fe) in degrading tetracycline is attributed to the fact that C-dots have the ability to act as acceptors and donors of electrons, thus promoting electron transfer and inhibiting electron-hole recombination. Moreover, the 2.5-carbon nanodots/MIL-100(Fe) also showed high stability after five cycles of the photodegradation reaction. The quenching experiment proved that the main active substances that degrade tetracycline were O2- and h+. The study of carbon nanodots /MIL-100(Fe) composite materials provides new thoughts and methods for the removal of organic pollutants.