| Literature DB >> 35292628 |
Anqi Zeng1,2,3, Wu Chen2, Kasper Dalgas Rasmussen2, Xuehong Zhu4,5, Maren Lundhaug6, Daniel B Müller6, Juan Tan7, Jakob K Keiding7, Litao Liu8, Tao Dai9, Anjian Wang10, Gang Liu11.
Abstract
In recent years, increasing attention has been given to the potential supply risks of critical battery materials, such as cobalt, for electric mobility transitions. While battery technology and recycling advancement are two widely acknowledged strategies for addressing such supply risks, the extent to which they will relieve global and regional cobalt demand-supply imbalance remains poorly understood. Here, we address this gap by simulating historical (1998-2019) and future (2020-2050) global cobalt cycles covering both traditional and emerging end uses with regional resolution (China, the U.S., Japan, the EU, and the rest of the world). We show that cobalt-free batteries and recycling progress can indeed significantly alleviate long-term cobalt supply risks. However, the cobalt supply shortage appears inevitable in the short- to medium-term (during 2028-2033), even under the most technologically optimistic scenario. Our results reveal varying cobalt supply security levels by region and indicate the urgency of boosting primary cobalt supply to ensure global e-mobility ambitions.Entities:
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Year: 2022 PMID: 35292628 PMCID: PMC8924274 DOI: 10.1038/s41467-022-29022-z
Source DB: PubMed Journal: Nat Commun ISSN: 2041-1723 Impact factor: 14.919
Fig. 1System definition of the global anthropogenic cobalt cycle and modeling framework for cobalt demand and secondary supply potentials.
BEV battery electric vehicles, PHEV plug-in hybrid electric vehicles, NMC lithium nickel manganese cobalt oxide, NCA(I) lithium nickel cobalt aluminum oxide, NCA(II) advanced NCA with lower cobalt content and higher energy density, LFP(I) lithium iron phosphate, LFP(II) new form of LFP (e.g., blade LFP battery developed by the company BYD), LMO lithium manganese oxide, Li-air lithium-air, Li-S lithium-sulfur, SSB solid-state battery, B-PEV battery for electric passenger vehicles, B-EB battery for electric buses, B-ESS battery for energy storage systems, B-CE&O battery for consumer electronics and other battery products, SA superalloy, CC cemented carbides, MAG magnets, CAT catalysts, PI pigments, OTH other end uses. Battery cathodes in black and red colors indicate state-of-the-art battery technologies and future battery technologies, respectively.
Fig. 2Historical cobalt stocks and flows at global and regional scales, 1998–2019.
a Cumulative global cobalt cycle, b cumulative cobalt apparent consumption (inflows to manufacturing) by sector by region, c cumulative net import (positive values) and net export (negative values) of cobalt-containing final products by sector by region, d cumulative demand (inflows to in-use stocks) by sector by region, and e in-use stocks by end use by region in 2019. All values are in metric kilotons as cobalt metallic equivalent.
Description and assumptions of key model parameters.
| Key parameters | Descriptions/Assumptions | Details |
|---|---|---|
| Cobalt intensity | The cobalt intensity of different battery cathode materials varies by each type[ | Supplementary Table |
| Battery cathode material market share | The cathode materials of the state-of-the-art battery cathode technologies are assumed to shift from NMC-111 toward NCA and NMC-811[ | Supplementary Figs. |
| The share of BEV/PHEV in EV sales | PHEV is assumed to transform gradually to BEV, and BEV will dominate the EV market in the future[ | Supplementary Figs. |
| Battery capacity of BEV/PHEV | The battery capacity for PHEV and BEV are both assumed to increase based on the prediction of IEA[ | Supplementary Figs. |
| EV market share | The EV market share is assumed to increase based on the prediction of IEA[ | Supplementary Figs. |
| Vehicle ownership | Vehicle ownership is assumed to grow or level off based on regional historical levels, their potential socioeconomic development, and mobility as a service pattern. | Supplementary Figs. |
| ESS stock | The global ESS stock is assumed to grow, based on the literature[ | Supplementary Fig. |
| Battery lifetime | The average lifetimes of B-PEV, B-EB, and B-ESS are assumed to be 8[ | Supplementary Table |
| Recycling rate | The recycling rates for each end use are assumed to rise by 10% in 2050 based on the historical levels[ | Supplementary Fig. |
| Cobalt stock per capita for traditional end uses | Assumptions are based on the historical cobalt stock levels and potential technology changes considering regional differences. | Supplementary Table |
| Population | The predicted population per region is based on the World Population Prospects 2019 published by the United Nations Population Division[ | Supplementary Table |
| Primary supply | The primary cobalt supply from ore from 2020 to 2030 and afterward is based on previous research[ | Supplementary Fig. |
Description of the seven selected scenarios.
| Scenarios | S1 | S2 | S3 | S4 | S5 | S6 | S7 |
|---|---|---|---|---|---|---|---|
| Descriptions/Assumptions | The EV market expands with the state-of-the-art battery cathode technology, with no changes in battery lifetime and recycling rate | High nickel battery technology with lower cobalt intensity penetrates the market from 2020 | New LFP battery technology with zero cobalt penetrates the market from 2020 | Next-generation cobalt-free battery technology penetrates the market from 2030 | Extending the battery lifetime through improved electrolyte technology | Improving the recycling technology of EoL products | The most optimistic scenario with the lowest demand, highest supply, and the most advantageous technologies |
| End-use categories | Emerging end uses | Emerging end uses | Emerging end uses | Emerging end uses | Emerging end uses | All end uses | All end uses |
| Battery cathode market shares | NMC-811 and NCA gradually dominate (100% by 2050), varying among the five regions | NMC-9.5.5/advanced NCA gradually dominate (100% by 2050) | New LFP gradually dominate (100% by 2050) | Li-S/Li-Air/SSB gradually dominate (100% by 2050) | NMC-811 and NCA gradually dominates (100% by 2050), varied among the five regions | NMC-811 and NCA gradually dominates (100% by 2050), varied among the five regions | New LFP gradually dominate (100% by 2050) |
| Battery lifetime (years) | B-PEV: 8 B-EB: 7 B-ESS: 10 | B-PE V: 8 B-EB: 7 B-ESS: 10 | B-PEV: 8 B-EB: 7 B-ESS: 10 | B-PEV: 8 B-EB: 7 B-ESS: 10 | B-PEV: 16 B-EB: 14 B-ESS: 20 | B-PEV: 8 B-EB: 7 B-ESS: 10 | B-PEV: 16 B-EB: 14 B-ESS: 20 |
| EoL recycling rate | Gradually rising by 10% for all recyclable end uses | Gradually rising by 10% for all recyclable end uses | Gradually rising by 10% for all recyclable end uses | Gradually rising by 10% for all recyclable end uses | Gradually rising by 10% for all recyclable end uses | Reaching 95% for all recyclable end uses by 2050 | Reaching 95% for all recyclable end uses by 2050 |
Fig. 3Prospective global cobalt demand (positive values), scrap generation (negative values), and total supply (primary + secondary) under the seven scenarios.
a S1: state-of-the-art battery cathode technology scenario as the reference scenario; b S2: low-cobalt battery cathode technology scenario; c S3: LFP-dominant cobalt-free battery cathode technology scenario; d S4: next-generation cobalt-free battery cathode technology scenario; e S5: extending battery lifetime scenario; f S6: high recycling rate scenario; and g S7: the most optimistic technology scenario. The scenarios are detailed in Table 2 in the Methods section. The primary-base and primary-high indicate two primary supply scenarios, as shown in Table 1 and Methods.
Fig. 4Prospective cumulative primary demand, domestic and total reserve, and corresponding supply security levels under the seven selected scenarios.
a The regional cumulative primary demand (gross demand minus secondary supply) under the seven scenarios from 2020 to 2050; b shares of domestic reserves by region in 2019; c shares of total reserves (domestic reserves plus overseas cobalt reserve ownership[88]) by region in 2019 and the primary cobalt supply security level during 2020–2050 measured by d domestic reserve divided by cumulative primary demand; e total reserve divided by cumulative primary demand; and f total reserve divided by cumulative primary apparent consumption (primary demand plus net export of cobalt final products, which are assumed the same as the 2019 levels).