Effects of multi-factors on the spatiotemporal variations of deep confined groundwater in coal mining regions, North China.

Natural processes and anthropogenic activities simultaneously control the long-term spatial and temporal variations of groundwater hydrogeochemistry in coalfields. In this study, the spatiotemporal variations and primary controlling factors of deep groundwater hydrogeochemistry in the Carboniferous limestone aquifer of the Huaibei coalfield, North China were investigated using cluster analysis combined with geological conditions, water-rock interactions and mining activities. The analysis data of 176 groundwater samples collected over five years from 20 monitoring wells were subdivided into six clusters through hierarchical cluster analysis. Moreover, principal component analysis, box plots and Piper and Stiff diagrams were employed to analyze the statistical and hydrogeochemical characteristics of each cluster, and to reveal the differences and connections between the clusters. The results show that there are significantly spatial variations in groundwater hydrogeochemistry, while the temporal variations are not evident with only a few notable exceptions. Geological conditions dominate the groundwater hydrogeochemistry by controlling the hydraulic connection between groundwater and meteoric water and the flow conditions of groundwater. Moreover, the types and degrees of diverse water-rock interactions in different regions are another important factor controlling the spatial variations of groundwater hydrogeochemistry. Anthropogenic activities are mainly pumping and drainage, which has led to the overall decline in groundwater levels and the temporal variations of hydrogeochemistry in some zones. The findings of this study not only have important implications for deep groundwater resources management in the Huaibei coalfield, but also provide a research template for other highly exploited coalfields in North China.