| Literature DB >> 35079414 |
Said Daoui1, Israa Muwafaq2, Emine Berrin Çınar2, Abdulmalik Abudunia3, Necmi Dege2, Noureddine Benchat1, Khalid Karrouchi4.
Abstract
The pyridazine ring in the title compound, C20H17ClN2O3, adopts a screw-boat conformation. The whole mol-ecule is flattened, the dihedral angles subtended by the least-squares plane of the central aromatic ring with those of the terminal benzene and pyridazine rings being 15.18 (19) and 11.23 (19)°, respectively. In the crystal, the mol-ecules are linked by pairs of N-H⋯O bonds into centrosymmetric dimers and by C-H⋯π contacts into columns. The results of the Hirshfeld surface analysis show that the most prominent inter-actions are H⋯H, accounting for 36.5% of overall crystal packing, and H⋯O/O⋯H (18.6% contribution) contacts. © Daoui et al. 2022.Entities:
Keywords: Hirshfeld surface; crystal structure; dihydropyridazin; hydrogen bonding
Year: 2022 PMID: 35079414 PMCID: PMC8739192 DOI: 10.1107/S205698902101238X
Source DB: PubMed Journal: Acta Crystallogr E Crystallogr Commun