Application of Fenton sludge coupled hydrolysis acidification in pretreatment of wastewater containing PVA: Performance and mechanisms.

Hydrolysis acidification (HA) is widely used in pretreatment of macromolecular refractory wastewater to improve its biodegradability. However, because the biological activity could be inhibited by macromolecular substances to a certain extent, its application is limited. In this study, polyvinyl alcohol (PVA), as a classic macromolecular pollutant in TPD wastewater, was treated by the Fenton sludge-coupled HA process to investigate the effects of Fenton sludge addition on the HA performance and identify the probable mechanisms behind it. The results showed that approximately 40% of macromolecular PVA was hydrolyzed into small molecular substances with molecular weight (Mw) < 105 in the Fenton sludge-added reactor. Meanwhile, acidification efficiency (AE), volatile fatty acid production increased by 20.8% and 92.05 mg/L with Fenton sludge addition. The values of BOD5/COD changed from 0.091 of influent to 0.26 and 0.32 of effluent from the simple HA process and Fenton sludge addition HA process, respectively. These results proved that biodegradability was improved by the two processes and the Fenton sludge addition had a positive effect on HA. Further analysis found that 2-lines ferrihydrite involved in Fenton sludge might serve as an electron acceptor to participate in extracellular respiratory. Besides, the Fe2+ observed a positive effect of the sludge characteristics in agreement with the higher activity of dehydrogenase and extracellular polymeric substances (EPS) production. This study suggested that Fenton sludge can be recycled and used as an iron source to enhance HA for industrial wastewater pretreatment.