Fabrication of NH2-MIL-125(Ti) nanodots on carbon fiber/MoS2-based weavable photocatalysts for boosting the adsorption and photocatalytic performance.

Metal-organic frameworks (MOFs) are prospective photocatalysts for removing pollutants. However, the large size of MOFs results in unsatisfactory photocatalytic performance, thus restricting their further usage. Herein, ultrasmall Ti MOF (NH2-MIL-125(Ti)) nanodots (diameter: < 10 nm) were prepared on carbon fiber (CF) (diameter: ∼7 μm) based MoS2 (thickness: ∼20 nm, length: ∼200 nm) via a facile method and used as an efficient and reusable photocatalyst. The weaved CF/MoS2/NH2-MIL-125(Ti) cloth (0.15 g, 4 × 4 cm2) shows good reusability with an easy reusing process. Compared with large size NH2-MIL-125(Ti) based sample, our well-prepared NH2-MIL-125(Ti) nanodots based sample shows the improved surface area (290.1 m2 g-1) and it can generate more reactive oxygen species (ROS), which enhance removal performance (81.1% levofloxacin (LVFX), 67.9% acid orange 7 (AO7), 94.3% methylene blue (MB) and 100% Cr(Ⅵ)) in 120 min. Additionally, the recycling test for 4 cycles indicates high stability. This work highlights the function of easy-recyclable NH2-MIL-125(Ti) nanodots-based heterojunctions in wastewater purification.