Literature DB >> 34925901

Crystal structure of 1,1'-(pyridine-2,6-di-yl)bis-[N-(pyridin-2-ylmeth-yl)methanaminium] dichloride dihydrate.

Layachi Merabet1,2, Marine Tassé1, Sonia Mallet-Ladeira3,1, Lakhemici Kaboub2, Isabelle Malfant1.   

Abstract

In the title compound, C19H23N5 2+·2Cl-·2H2O, the two pyridine side arms are not coplanar, with the terminal pyridine rings subtending a dihedral angle of 26.45 (6)°. In the crystal, hydrogen bonds, inter-molecular C-H⋯Cl contacts and a weak C-H⋯O inter-action connect the mol-ecule with neighbouring chloride counter-anions and lattice water mol-ecules. The crystal packing also features by π-π inter-actions with centroid-centroid distances of 3.4864 (12) and 3.5129 (13) Å. © Merabet et al. 2021.

Entities:  

Keywords:  crystal structure; hydrogen bonding; π–π inter­actions

Year:  2021        PMID： 34925901      PMCID： PMC8647756          DOI： 10.1107/S205698902101183X

Source DB:  PubMed          Journal:  Acta Crystallogr E Crystallogr Commun


  16 in total

1.  Photoactive Ruthenium Nitrosyls: Effects of Light and Potential Application as NO Donors.

Authors:  Michael J Rose; Pradip K Mascharak
Journal:  Coord Chem Rev       Date:  2008-10-01       Impact factor: 22.315

2.  Unusual role of solvents in the syntheses of {Fe-NO}6,7 nitrosyls derived from a ligand with carboxamido nitrogen and thiolato sulfur donors.

Authors:  Todd C Harrop; Marilyn M Olmstead; Pradip K Mascharak
Journal:  Inorg Chem       Date:  2005-10-03       Impact factor: 5.165

3.  New pyridine carboxamide ligands and their complexation to copper(II). X-Ray crystal structures of mono-, di, tri- and tetranuclear copper complexes.

Authors:  Sneh L Jain; Pravat Bhattacharyya; Heather L Milton; Alexandra M Z Slawin; Joe A Crayston; J Derek Woollins
Journal:  Dalton Trans       Date:  2004-02-23       Impact factor: 4.390

Review 4.  Fiat Lux: selective delivery of high flux of nitric oxide (NO) to biological targets using photoactive metal nitrosyls.

Authors:  Michael J Rose; Pradip K Mascharak
Journal:  Curr Opin Chem Biol       Date:  2008-04       Impact factor: 8.822

5.  Formation of a triply bridged mu-oxo diiron(III) core stabilized by two deprotonated carboxamide groups upon photorelease of NO from a [Fe-NO]6 iron nitrosyl.

Authors:  Aura A Eroy-Reveles; C Gianna Hoffman-Luca; Pradip K Mascharak
Journal:  Dalton Trans       Date:  2007-12-07       Impact factor: 4.390

6.  Incorporation of a designed ruthenium nitrosyl in PolyHEMA hydrogel and light-activated delivery of NO to myoglobin.

Authors:  Genevieve M Halpenny; Marilyn M Olmstead; Pradip K Mascharak
Journal:  Inorg Chem       Date:  2007-07-06       Impact factor: 5.165

7.  Light-triggered eradication of Acinetobacter baumannii by means of NO delivery from a porous material with an entrapped metal nitrosyl.

Authors:  Brandon J Heilman; Jessica St John; Scott R J Oliver; Pradip K Mascharak
Journal:  J Am Chem Soc       Date:  2012-05-23       Impact factor: 15.419

8.  SHELXT - integrated space-group and crystal-structure determination.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A Found Adv       Date:  2015-01-01       Impact factor: 2.290

9.  Crystal structure refinement with SHELXL.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr C Struct Chem       Date:  2015-01-01       Impact factor: 1.172

10.  Mercury 4.0: from visualization to analysis, design and prediction.

Authors:  Clare F Macrae; Ioana Sovago; Simon J Cottrell; Peter T A Galek; Patrick McCabe; Elna Pidcock; Michael Platings; Greg P Shields; Joanna S Stevens; Matthew Towler; Peter A Wood
Journal:  J Appl Crystallogr       Date:  2020-02-01       Impact factor: 3.304
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.