| Literature DB >> 34925898 |
Zeliha Atioğlu1, Mehmet Akkurt2, Namiq Q Shikhaliyev3, Ulviyya F Askerova3, Sevinc H Mukhtarova3, Rizvan K Askerov3, Ajaya Bhattarai4.
Abstract
In the title compound, C16H14N2O2, the 2,3-di-hydro-1-benzo-furan ring system is essentially planar and makes a dihedral angle of 3.69 (7)° with the di-methyl-phenyl ring. The mol-ecular conformation is stabilized by an intra-molecular N-H⋯O hydrogen bond with an S(6) ring motif. In the crystal, mol-ecules are connected by C-H⋯π and π-π stacking inter-actions, forming a layer lying parallel to the (11) plane. One methyl group is disordered over two orientations, with occupancies of 0.67 (4) and 0.33 (4). Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯H (51.2%), O⋯H/H⋯O (17.9%), C⋯H/H⋯C (15.2%) and C⋯C (8.1%) contacts. © Atioğlu et al. 2021.Entities:
Keywords: C—H⋯π interactions; Hirshfeld surface analysis; crystal structure; intramolecular N—H⋯O interactions
Year: 2021 PMID: 34925898 PMCID: PMC8647749 DOI: 10.1107/S2056989021011749
Source DB: PubMed Journal: Acta Crystallogr E Crystallogr Commun