MXene-Coated Wrinkled Fabrics for Stretchable and Multifunctional Electromagnetic Interference Shielding and Electro/Photo-Thermal Conversion Applications.

Stretchability and multifunctional heating abilities are highly desired for wearable electromagnetic interference (EMI) shielding fabrics to tackle the growing electromagnetic pollution for special crowd, such as pregnant women. Herein, we fabricated stretchable MXene-coated thermoplastic polyurethane (TPU) fabrics by simple uniaxial prestretching and spraying methods. The obtained unique wrinkled structure endowed the film with effective strain-invariant electrical conductivity and EMI shielding properties. Specifically, the prepared stretchable film with an extremely low MXene loading (0.417 mg cm-2) exhibited a stable EMI shielding effectiveness of approximately 30 dB under 50% tensile strain and durability during stretching and bending cycles. More importantly, owing to the high electrical conductivity and localized surface plasmon resonance (LSPR) effect of the MXene layer, the stretchable fabrics exhibited excellent Joule heating (up to 104 °C at a voltage of 5 V) and superior photothermal conversion abilities. Moreover, the unique wrinkled MXene-coating layer not only endows the fabrics with stretchable heat abilities but also enhances the photothermal conversion performance by increasing the light absorption area and travel path. We believe that this study offers a novel strategy for the versatile design of stretchable and multifunctional wearable shielding fabrics.