Unveiling the boosting of metal organic cage leaching substance on the electrocatalytic oxygen evolution reaction.

Catalysts often undergo changes during the process of catalytic reactions, which makes the whole catalytic reaction system complicated and brings about much difficulty for the exploration of catalytic mechanism. Herein, we report that an octahedral metal organic cage (MOC) with stress was directionally transformed into two-dimensional nanoarrays maintaining the structure of precursor and new soluble low-nuclear complexes during the electrocatalytic oxygen evolution reaction (OER). The in-situ generated miscible electrocatalyst exhibits an overpotential as low as 197 mV at 10 mA cm-2, with a high electrochemical stability up to 5 h. Notably, the miscible catalyst can be used as bifunctional electrocatalyst for OER and hydrogen evolution reaction (HER) and exhibits an ultra-low overpotential of 293 mV, even achieve overall water splitting under the voltage provided by a 1.5 V AA battery. As revealed by density functional theory simulations, the position of SO42- in MOC heterogeneous catalyst is regulated by the soluble low-nuclear complexes to reduce the activation energy of the reaction, leading to an optimization of the OER activity for the reaction system. This work provides a new strategy for the rational design of high-efficiency electrocatalytic system.