Literature DB >> 34850783

Red-light-activatable ruthenium phthalocyanine catalysts.

Yuta Ishikawa1, Tatsuya Kameyama2,3, Tsukasa Torimoto2, Hajime Maeda1, Masahito Segi1, Taniyuki Furuyama1,3.   

Abstract

Phthalocyanine ruthenium complexes were identified as red-light activatable catalysts for trifluoromethylation reactions. The red-light mediated chlorotrifluoromethylation of alkenes could proceed without any sacrificial reducing reagents. This reaction exhibited good compatibility with a blue-light-absorbing substrate, while under irradiation with blue light, i.e., under traditional photoreaction conditions, this substrate decomposed completely.

Entities:  

Year:  2021        PMID: 34850783     DOI: 10.1039/d1cc06307c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Red Light-Based Dual Photoredox Strategy Resembling the Z-Scheme of Natural Photosynthesis.

Authors:  Felix Glaser; Oliver S Wenger
Journal:  JACS Au       Date:  2022-06-10

2.  Subphthalocyanine capsules: molecular reactors for photoredox transformations of fullerenes.

Authors:  Marta Moreno-Simoni; Tomás Torres; Gema de la Torre
Journal:  Chem Sci       Date:  2022-07-19       Impact factor: 9.969

  2 in total

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