High-efficiency adsorption of Cd(II) and Co(II) by ethylenediaminetetraacetic dianhydride-modified orange peel as a novel synthesized adsorbent.

The treatment of heavy metal (HM) wastewater is a critical and considerable challenge. Fruit peel-based HM adsorption is a promising way for the water pollution control and the reuse of agricultural waste. In this study, a novel adsorbent based on orange peel was synthesized for the first time by introducing abundant -COO groups with ethylenediaminetetraacetic dianhydride (EDTAD) to eliminate Cd(II) and Co(II) of sewage solution. The synthesized adsorbent displayed excellent adsorption capacity of 51.020 and 40.486 mg/g for Cd(II) and Co(II), respectively, and the adsorption equilibrium was achieved within 5 min, following the Langmuir isotherm model and the pseudo-second-order model. Surface characterization of adsorbents by scanning electron microscopy-energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy confirmed that ion exchange, complexation, and physical adsorption could occur during the adsorption process. The rapid and highly efficient adsorption performance suggests EDTAD-modified synthesized orange peel possesses great potential for HM removal from sewage systems.