Emerging Two-Dimensional Covalent and Coordination Polymers for Stable Lithium Metal Batteries: From Liquid to Solid.

Lithium metal anodes (LMAs) have attracted much attention in recent years because of their high theoretical capacity (3860 mAh g-1) and low electrochemical potential (-3.040 V vs standard hydrogen electrode). Lithium metal can be coupled with various cathodes to construct high-energy-density lithium metal batteries (LMBs) which hold great promise for next-generation batteries. However, the unstable solid electrolyte interphases (SEIs) and the uncontrollable lithium dendrite growth severely hinder the commercial development of LMAs. The emerging 2D polymers (2DPs), which possess high mechanical flexibility, high specific surface area, abundant surface chemistry, and rich chemical modification characteristics, have shown great advantages in addressing the inherent issues of LMAs. Herein, the current progress of 2DPs for stable and dendrite-free LMAs in liquid- and solid-based batteries is comprehensively reviewed. Some perspectives for the application of 2DPs in LMBs are also discussed. It is believed that the emerging 2DPs will provide insights into developing high-energy-density LMBs and beyond.