Chang Da1, Xiongyu Chen1, Jingyi Zhu1, Shehab Alzobaidi1, Gaurav Garg1, Keith P Johnston2. 1. McKetta Department of Chemical Engineering and Texas Materials Institute, The University of Texas, Austin, TX, USA. 2. McKetta Department of Chemical Engineering and Texas Materials Institute, The University of Texas, Austin, TX, USA. Electronic address: kpj@che.utexas.edu.
Abstract
HYPOTHESIS: Surface active anionic nanoparticles (NPs) with strategically designed covalent ligands may be combined with a liked-charged surfactant to form a highly elastic gas-water interface leading to highly stable gas/water foams. EXPERIMENTS: The colloidal stability of the NPs was determined by dynamic light scattering, and the surface elastic dilational modulus E' of the interface by sinusoidal oscillation of a pendant droplet at 0.1 Hz, which was superimposed on large-amplitude compression-expansion cycles. The foam stability was measured with optical microscopy of the bubble size distribution and from the macroscopic foam height. FINDINGS: The NPs played the key role the formation of a highly elastic air-water interface with a high E' despite a surfactant level well above the critical micelle concentration. Unlike the case for most previous studies, the NP amphiphilicity was essentially independent of the surfactant given the very low adsorption of the surfactant on the like-charged NP surfaces. With high E' values, both coalescence and coarsening were reduced leading to highly foam up to 80 °C. However, the surfactant facilitated foam generation at much lower shear rates than with NPs alone. The tuning of NP surfaces with ligands for colloidal stability in brine and simultaneously high amphiphilicity at the gas-water interface, over a wide range in surfactant concentration, is of broad interest for enabling the design of highly stable foams.
HYPOTHESIS: Surface active anionic nanoparticles (NPs) with strategically designed covalent ligands may be combined with a liked-charged surfactant to form a highly elastic gas-water interface leading to highly stable gas/water foams. EXPERIMENTS: The colloidal stability of the NPs was determined by dynamic light scattering, and the surface elastic dilational modulus E' of the interface by sinusoidal oscillation of a pendant droplet at 0.1 Hz, which was superimposed on large-amplitude compression-expansion cycles. The foam stability was measured with optical microscopy of the bubble size distribution and from the macroscopic foam height. FINDINGS: The NPs played the key role the formation of a highly elastic air-water interface with a high E' despite a surfactant level well above the critical micelle concentration. Unlike the case for most previous studies, the NP amphiphilicity was essentially independent of the surfactant given the very low adsorption of the surfactant on the like-charged NP surfaces. With high E' values, both coalescence and coarsening were reduced leading to highly foam up to 80 °C. However, the surfactant facilitated foam generation at much lower shear rates than with NPs alone. The tuning of NP surfaces with ligands for colloidal stability in brine and simultaneously high amphiphilicity at the gas-water interface, over a wide range in surfactant concentration, is of broad interest for enabling the design of highly stable foams.