Literature DB >> 34706938

Topological barriers to defect nucleation generate large mechanical forces in an ordered fluid.

Bruno Zappone1, Roberto Bartolino2.   

Abstract

Common fluids cannot sustain static mechanical stresses at the macroscopic scale because they lack molecular order. Conversely, crystalline solids exhibit long-range order and mechanical strength at the macroscopic scale. Combining the properties of fluids and solids, liquid crystal films respond to mechanical confinement by both flowing and generating static forces. The elastic response, however, is very weak for film thicknesses exceeding 10 nm. In this study, the mechanical strength of a fluid film was enhanced by introducing topological defects in a cholesteric liquid crystal, producing unique viscoelastic and optomechanical properties. The cholesteric was confined under strong planar anchoring conditions between two curved surfaces with sphere-sphere contact geometry similar to that of large colloidal particles, creating concentric dislocation loops. During surface retraction, the loops shrank and periodically disappeared at the surface contact point, where the cholesteric helix underwent discontinuous twist transitions, producing weak oscillatory surface forces. On the other hand, new loop nucleation was frustrated by a topological barrier during fluid compression, creating a metastable state. This generated exceptionally large forces with a range exceeding 100 nm as well as extended blueshifts of the photonic bandgap. The metastable cholesteric helix eventually collapsed under a high compressive load, triggering a stick-slip-like cascade of defect nucleation and twist reconstruction events. These findings were explained using a simple theoretical model and suggest a general approach to enhance the mechanical strength of one-dimensional periodic materials, particularly cholesteric colloid mixtures.

Entities:  

Keywords:  dislocations; liquid crystals; material hardening; nucleation; surface forces

Year:  2021        PMID: 34706938      PMCID: PMC8612233          DOI: 10.1073/pnas.2110503118

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  21 in total

1.  Anchoring-mediated interaction of edge dislocations with bounding surfaces in confined cholesteric liquid crystals.

Authors:  I I Smalyukh; O D Lavrentovich
Journal:  Phys Rev Lett       Date:  2003-02-26       Impact factor: 9.161

2.  Bistable defect structures in blue phase devices.

Authors:  A Tiribocchi; G Gonnella; D Marenduzzo; E Orlandini; F Salvadore
Journal:  Phys Rev Lett       Date:  2011-12-01       Impact factor: 9.161

3.  Reconfigurable interactions and three-dimensional patterning of colloidal particles and defects in lamellar soft media.

Authors:  Rahul P Trivedi; Ivan I Klevets; Bohdan Senyuk; Taewoo Lee; Ivan I Smalyukh
Journal:  Proc Natl Acad Sci U S A       Date:  2012-03-12       Impact factor: 11.205

4.  Direct nanomechanical measurement of an anchoring transition in a nematic liquid crystal subject to hybrid anchoring conditions.

Authors:  Marina Ruths; Bruno Zappone
Journal:  Langmuir       Date:  2012-05-23       Impact factor: 3.882

5.  Direct Measurement of the Interaction between Two Ordering Surfaces Confining a Presmectic Film.

Authors: 
Journal:  Phys Rev Lett       Date:  1994-12-26       Impact factor: 9.161

6.  Nonlinear smectic elasticity of helical state in cholesteric liquid crystals and helimagnets.

Authors:  Leo Radzihovsky; T C Lubensky
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2011-05-02

7.  Direct measurements of structural forces and twist transitions in cholesteric liquid crystal films with a surface force apparatus.

Authors:  Weichao Zheng; Carla Sofia Perez-Martinez; Gia Petriashvili; Susan Perkin; Bruno Zappone
Journal:  Soft Matter       Date:  2019-06-19       Impact factor: 3.679

8.  Cholesteric pitch transitions induced by mechanical strain.

Authors:  I Lelidis; G Barbero; A L Alexe-Ionescu
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2013-02-13

9.  Self-assembly of colloid-cholesteric composites provides a possible route to switchable optical materials.

Authors:  K Stratford; O Henrich; J S Lintuvuori; M E Cates; D Marenduzzo
Journal:  Nat Commun       Date:  2014-06-18       Impact factor: 14.919

10.  Controlling Gaussian and mean curvatures at microscale by sublimation and condensation of smectic liquid crystals.

Authors:  Dae Seok Kim; Yun Jeong Cha; Mun Ho Kim; Oleg D Lavrentovich; Dong Ki Yoon
Journal:  Nat Commun       Date:  2016-01-04       Impact factor: 14.919

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