Structural Chemistry of Giant Metal Based Supramolecules.

The review presents a bird-eye view on the state of research in the field of giant nonbiological discrete metal complexes and ions of nanometer size, which are structurally characterized by means of single-crystal X-ray diffraction, using the crystal structure as a common key feature. The discussion is focused on the main structural features of the metal clusters, the clusters containing compact metal oxide/hydroxide/chalcogenide core, ligand-based metal-organic cages, and supramolecules as well as on the aspects related to the packing of the molecules or ions in the crystal and the methodological aspects of the single-crystal neutron and X-ray diffraction of these compounds.