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Literature DB >> 34450005

Molecular Main Group Metal Hydrides.

Matthew M D Roy¹, Alvaro A Omaña², Andrew S S Wilson³, Michael S Hill³, Simon Aldridge¹, Eric Rivard².

Abstract

This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12-16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated catalysis. While this review is comprehensive in nature, focus will be given to research appearing in the open literature since 2001.

Entities: Chemical

Mesh：
Catalysis
Metals

Substances：
Metals

Year: 2021 PMID： 34450005 DOI： 10.1021/acs.chemrev.1c00278

Source DB: PubMed Journal: Chem Rev ISSN： 0009-2665 Impact factor: 60.622

Keyword Cloud
Cited

7 in total

1. Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal-Ligand Cooperation.

Authors: Yaoyu Liang; Uttam Kumar Das; Jie Luo; Yael Diskin-Posner; Liat Avram; David Milstein
Journal: J Am Chem Soc Date: 2022-10-04 Impact factor: 16.383

Review 2. s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds.

Authors: Marc Magre; Marcin Szewczyk; Magnus Rueping
Journal: Chem Rev Date: 2022-03-07 Impact factor: 72.087

3. An NHC-Stabilized H₂ GeBH₂ Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains.

Authors: Matthias T Ackermann; Michael Seidl; Fuwei Wen; Michael J Ferguson; Alexey Y Timoshkin; Eric Rivard; Manfred Scheer
Journal: Chemistry Date: 2021-11-24 Impact factor: 5.020

4. Geometrically Constrained Cationic Low-Coordinate Tetrylenes: Highly Lewis Acidic σ-Donor Ligands in Catalytic Systems.

Authors: Philip M Keil; Terrance J Hadlington
Journal: Angew Chem Int Ed Engl Date: 2022-01-11 Impact factor: 16.823

Molecular Main Group Metal Hydrides.

1. Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal-Ligand Cooperation.

Review 2. s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds.

3. An NHC-Stabilized H₂ GeBH₂ Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains.

4. Geometrically Constrained Cationic Low-Coordinate Tetrylenes: Highly Lewis Acidic σ-Donor Ligands in Catalytic Systems.

5. A Brønsted Acidic Gallium Hydride: Facile Interconversion of NNNN-Macrocycle Supported [Ga^I ]⁺ and [Ga^III H]².

6. Molecular Ln(III)-H-E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb).

7. In Situ Grignard Metalation Method for the Synthesis of Hauser Bases.

Molecular Main Group Metal Hydrides.

1. Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal-Ligand Cooperation.

Review 2. s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds.

3. An NHC-Stabilized H2 GeBH2 Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains.

4. Geometrically Constrained Cationic Low-Coordinate Tetrylenes: Highly Lewis Acidic σ-Donor Ligands in Catalytic Systems.

5. A Brønsted Acidic Gallium Hydride: Facile Interconversion of NNNN-Macrocycle Supported [GaI ]+ and [GaIII H]2.

6. Molecular Ln(III)-H-E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb).

7. In Situ Grignard Metalation Method for the Synthesis of Hauser Bases.

3. An NHC-Stabilized H₂ GeBH₂ Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains.

5. A Brønsted Acidic Gallium Hydride: Facile Interconversion of NNNN-Macrocycle Supported [Ga^I ]⁺ and [Ga^III H]².