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Literature DB >> 34366484

Binding a Meridional Ligand in a Facial Geometry: A Square Peg in a Round Hole.

Briana R Schrage¹, Dominick Vitale¹, Kimberly A Kelly², Victor N Nemykin³, Richard S Herrick², Christopher J Ziegler¹.

Abstract

The bis(pyridylimino)isoindoline (BPI) ligand is a tridentate chelate that binds to metals via a meridional coordination mode. However, when this ligand forms a complex with Re(CO)3, an almost exclusively facial moiety, the BPI ligand deforms to coordinate in a facial mode. We have in-vestigated this deformation via structural and theoretical means, and the non-planar binding mode of the ligand bathochromically shifts the metal to ligand charge transfer (MLCT) transition.

Entities: Chemical

Year: 2020 PMID： 34366484 PMCID： PMC8340874 DOI： 10.1016/j.jorganchem.2020.121331

Source DB: PubMed Journal: J Organomet Chem ISSN： 0022-328X Impact factor: 2.369

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References

11 in total

1. Using Hydrazine to Link Ferrocene with Re(CO)₃: A Modular Approach.

Authors: Kullapa Chanawanno; Hannah M Rhoda; Abed Hasheminasab; Laura A Crandall; Alexander J King; Richard S Herrick; Victor N Nemykin; Christopher J Ziegler
Journal: J Organomet Chem Date: 2016-06-07 Impact factor: 2.369

2. Re(CO)₃-Templated Synthesis of Semihemiporphyrazines.

Authors: Allen J Osinski; Tanner Blesener; Abed Hasheminasab; Cole Holstrom; Victor N Nemykin; Richard S Herrick; Christopher J Ziegler
Journal: Inorg Chem Date: 2016-12-07 Impact factor: 5.165

3. Re(CO)₃-Templated Synthesis of α-Amidinoazadi(benzopyrro)methenes.

Authors: Allen J Osinski; Daniel L Morris; Richard S Herrick; Christopher J Ziegler
Journal: Inorg Chem Date: 2017-11-27 Impact factor: 5.165

4. Luminescent rhenium(I) tricarbonyl complexes with pyrazolylamidino ligands: photophysical, electrochemical, and computational studies.

Authors: Patricia Gómez-Iglesias; Fabrice Guyon; Abderrahim Khatyr; Gilles Ulrich; Michael Knorr; Jose Miguel Martín-Alvarez; Daniel Miguel; Fernando Villafañe
Journal: Dalton Trans Date: 2015-09-21 Impact factor: 4.390

5. Iron(III) complexes with meridional ligands as functional models of intradiol-cleaving catechol dioxygenases.

Authors: Tünde Váradi; József S Pap; Michel Giorgi; László Párkányi; Tamás Csay; Gábor Speier; József Kaizer
Journal: Inorg Chem Date: 2013-01-15 Impact factor: 5.165

6. Cobalt alkyl complexes of a new family of chiral 1,3-bis(2-pyridylimino)isoindolates and their application in asymmetric hydrosilylation.

Authors: Désirée C Sauer; Hubert Wadepohl; Lutz H Gade
Journal: Inorg Chem Date: 2012-11-15 Impact factor: 5.165

Binding a Meridional Ligand in a Facial Geometry: A Square Peg in a Round Hole.

1. Using Hydrazine to Link Ferrocene with Re(CO)₃: A Modular Approach.

2. Re(CO)₃-Templated Synthesis of Semihemiporphyrazines.

3. Re(CO)₃-Templated Synthesis of α-Amidinoazadi(benzopyrro)methenes.

4. Luminescent rhenium(I) tricarbonyl complexes with pyrazolylamidino ligands: photophysical, electrochemical, and computational studies.

5. Iron(III) complexes with meridional ligands as functional models of intradiol-cleaving catechol dioxygenases.

6. Cobalt alkyl complexes of a new family of chiral 1,3-bis(2-pyridylimino)isoindolates and their application in asymmetric hydrosilylation.

7. Luminescent Rhenium(I) Pyridyldiaminocarbene Complexes: Photophysics, Anion-Binding, and CO2-Capturing Properties.

8. Re(CO)3-Templated Formation of Aza(dibenzo)dipyrromethenes.

9. Palladium(II) complexes of unsymmetrical CNN pincer ligands.

10. Catechol oxidase and phenoxazinone synthase activity of a manganese(II) isoindoline complex.