Literature DB >> 34343586

Thermoplastic mung bean starch/natural rubber/sericin blends for improved oil resistance.

Pornchai Rachtanapun1, Araya Kodsangma2, Nattagarn Homsaard2, Sudarut Nadon2, Pensak Jantrawut3, Warintorn Ruksiriwanich3, Phisit Seesuriyachan1, Noppol Leksawasdi1, Yuthana Phimolsiripol1, Thanongsak Chaiyaso4, Suphat Phongthai4, Sarana Rose Sommano5, Charin Techapun2, Toshiaki Ougizawa6, Thosak Kittikorn7, Sutee Wangtueai8, Joe M Regenstein9, Kittisak Jantanasakulwong10.   

Abstract

Oil resistant thermoplastic elastomers (TPE) were prepared using mung bean thermoplastic starch (MTPS) blending with rubbers and sericin. Sericin was incorporated into MTPS as a compatibilizer. MTPS with sericin (MTPSS) was blended with natural rubber (NR) and epoxidized NR (ENR). Sericin at 5% improved the tensile strength (10 MPa), elastic recovery (52%) and morphology of the MTPSS/ENR blend. The mechanical properties, elastic recovery and morphology of the MTPSS5/NR blend were improved by the addition of ENR. The MTPSS/ENR showed palm (28%) and motor oils (8%) swelling resistance because of the hydrophilicity of MTPS and high polarity of ENR. The MTPSS/ENR/NR showed gasoline swelling resistance (104%) because of the hydrophilicity of MTPS and low polarity of NR. FTIR confirmed a reaction between the -NH groups of sericin and the epoxy groups of ENR. This reaction improved the compatibility, mechanical properties, elastic recovery, morphology and oils swelling resistance of the blends.
Copyright © 2021 Elsevier B.V. All rights reserved.

Entities:  

Keywords:  Epoxidized natural rubber; Mung bean; Oil resistance; Sericin; Thermoplastic elastomer; Thermoplastic starch; Vigna radiata

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Year:  2021        PMID: 34343586     DOI: 10.1016/j.ijbiomac.2021.07.187

Source DB:  PubMed          Journal:  Int J Biol Macromol        ISSN: 0141-8130            Impact factor:   6.953


  2 in total

Review 1.  Natural Fiber-Reinforced Thermoplastic ENR/PVC Composites as Potential Membrane Technology in Industrial Wastewater Treatment: A Review.

Authors:  A S Norfarhana; R A Ilyas; N Ngadi; Shubham Sharma; Mohamed Mahmoud Sayed; A S El-Shafay; A H Nordin
Journal:  Polymers (Basel)       Date:  2022-06-15       Impact factor: 4.967

2.  Corn starch reactive blending with latex from natural rubber using Na+ ions augmented carboxymethyl cellulose as a crosslinking agent.

Authors:  Noppol Leksawasdi; Thanongsak Chaiyaso; Pornchai Rachtanapun; Sarinthip Thanakkasaranee; Pensak Jantrawut; Warintorn Ruksiriwanich; Phisit Seesuriyachan; Yuthana Phimolsiripol; Charin Techapun; Sarana Rose Sommano; Toshiaki Ougizawa; Kittisak Jantanasakulwong
Journal:  Sci Rep       Date:  2021-09-28       Impact factor: 4.379

  2 in total

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