Refueling emission of volatile organic compounds from China 6 gasoline vehicles.

Vehicular refueling emission is a potential source of urban atmospheric volatile organic compounds (VOCs) that is not well understood and controlled. China 6 vehicles have been equipped with the onboard refueling vapor recovery (ORVR) system to cut down refueling emissions, while the emission characteristics and reduction effectiveness are rarely reported. In this study, we conducted laboratory tests to measure the refueling emissions from ten China 6 vehicles and three China 5 vehicles (refueling-emission-uncontrolled, REU) and developed an inventory in a typical middle-sized Chinese city (Langfang) to explore the emission reduction resulted from relevant policies. Compared with headspace vapor and refueling vapor from REU vehicles, the emission profiles for China 6 vehicles are consist of considerably higher proportions of small alkanes and alkenes (C2-C3) and lower proportions of C6-C8 hydrocarbons. Such differences indicate that the headspace vapor profiles are incapable of representing the refueling emission for China 6 vehicles. The market-share-weighting emission factors (EFs) of total hydrocarbons (THCs) and total VOCs for China 6 vehicles are 11.2 mg/L and 6.4 mg/L, respectively, corresponding to control efficiency of approximately 98.8% compared with the REU vehicles. Based on the real-world EFs and the fuel consumption in Langfang, a refueling emission inventory with high spatiotemporal resolution is developed. The total refueling emission of THCs in Langfang is approximately 190.6 tons in 2018 and will likely decline to 25.0 tons in 2035. The implementation of the ORVR will contribute to 90% of the refueling emission reduction in 2035.