Long-term stability of arsenic calcium residue (ACR) treated with FeSO4 and H2SO4: Function of H+ and Fe(Ⅱ).

Arsenic calcium residue (ACR) generated from the As-bearing wastewater treatment is highly hazardous due to high content of available As, which was seeking a suitable method for safe disposal such as stabilization treatment. In this study, the stabilization of available As in ACR was performed by combined treatment with FeSO4 and H2SO4. After stabilization treatment, the As leaching concentrations extracted by China Standard Leaching Test (CSLT, HJ/T299-2007) decreased significantly from 162 mg/L to less than the Chinese regulation limit of 1.2 mg/L. And FeSO4-H2SO4 treated ACR could maintain good long-term stability even after cured for 365 days. The stabilization mechanism for available As in ACR using leaching tests, sequential extraction analysis, XPS, XRD, and SEM-EDS was investigated. H+ from H2SO4 and Fe(Ⅱ) hydrolysis was committed to the full release of available As. Reactive oxygen species (ROSs) produced from Fe(Ⅱ) oxygenation drove the oxidation of As(Ⅲ) to As(Ⅴ). The release As was stabilized by forming stable Fe-O-As complexes (FeAsO4·xFe(OH)3). Moreover, this study also presented an effective and feasible method for ACR disposal.