Ratiometric dual-emission of Rhodamine-B grafted carbon dots for full-range solvent components detection.

Quick and visual detection of component contents, such as water, in a mixed solvent is important for many practical applications, and a full range detection is especially preferred. In this work, a carbon dots based ratiometric fluorescent sensor was synthesized by grafting fluorescent group (Rhodamine B, RhB) on carbon dots, and the dual emission peaks exhibited a linear ratiometric response with the change of polarity and hydrogen bond of Solvent Hansen solubility parameters. This responsive behavior is attributed to surface state photoluminescence mechanisms, and has been used for the quantitative detection of water content in ethanol with an excellent linear relationship (R2 = 0.996), a low detection limit (0.2%), and a full detection range (0-100%). Furthermore, a paper-based ratiometric fluorescence sensing strip is also demonstrated, which exhibits good storage stability and sensitivity. This study suggests that RhB grafted carbon dots could be feasibly and effectively used as ratiometric fluorescent sensors for solvent content detection.