Literature DB >> 34230515

Inversely polarized thermo-electrochemical power generation via the reaction of an organic redox couple on a TiO2/Ti mesh electrode.

Hiroto Eguchi1, Takashi Kobayashi2, Teppei Yamada3,4, David S Rivera Rocabado5, Takayoshi Ishimoto6,7, Miho Yamauchi8,9,10.   

Abstract

We demonstrate thermo-electrochemical (TEC) conversion using a biocompatible redox couple of lactic acid and pyruvic acid on earth-abundant TiO2. The TEC cell exhibited a positive Seebeck coefficient of 1.40 mV K-1. DFT calculations figured out that the adsorption of intermediate species and protons on TiO2 controls both the redox reaction and current polarity.

Entities:  

Year:  2021        PMID： 34230515     DOI： 10.1038/s41598-021-93269-7

Source DB:  PubMed          Journal:  Sci Rep        ISSN： 2045-2322            Impact factor:   4.379


  12 in total

1.  Harvesting waste thermal energy using a carbon-nanotube-based thermo-electrochemical cell.

Authors:  Renchong Hu; Baratunde A Cola; Nanda Haram; Joseph N Barisci; Sergey Lee; Stephanie Stoughton; Gordon Wallace; Chee Too; Michael Thomas; Adrian Gestos; Marilou E Dela Cruz; John P Ferraris; Anvar A Zakhidov; Ray H Baughman
Journal:  Nano Lett       Date:  2010-03-10       Impact factor: 11.189

2.  Association entropy in adsorption processes.

Authors:  N Ben-Tal; B Honig; C K Bagdassarian; A Ben-Shaul
Journal:  Biophys J       Date:  2000-09       Impact factor: 4.033

3.  Opportunities and challenges for a sustainable energy future.

Authors:  Steven Chu; Arun Majumdar
Journal:  Nature       Date:  2012-08-16       Impact factor: 49.962

4.  Optimization of the thermoelectric figure of merit in the conducting polymer poly(3,4-ethylenedioxythiophene).

Authors:  Olga Bubnova; Zia Ullah Khan; Abdellah Malti; Slawomir Braun; Mats Fahlman; Magnus Berggren; Xavier Crispin
Journal:  Nat Mater       Date:  2011-05-01       Impact factor: 43.841

5.  Calculation of standard transformed Gibbs energies and standard transformed enthalpies of biochemical reactants.

Authors:  R A Alberty
Journal:  Arch Biochem Biophys       Date:  1998-05-01       Impact factor: 4.013

Review 6.  Biomolecular electrostatics and solvation: a computational perspective.

Authors:  Pengyu Ren; Jaehun Chun; Dennis G Thomas; Michael J Schnieders; Marcelo Marucho; Jiajing Zhang; Nathan A Baker
Journal:  Q Rev Biophys       Date:  2012-11       Impact factor: 5.318

7.  Comparison of Implicit and Explicit Solvent Models for the Calculation of Solvation Free Energy in Organic Solvents.

Authors:  Jin Zhang; Haiyang Zhang; Tao Wu; Qi Wang; David van der Spoel
Journal:  J Chem Theory Comput       Date:  2017-03-06       Impact factor: 6.006

8.  Electrochemical hydrogenation of non-aromatic carboxylic acid derivatives as a sustainable synthesis process: from catalyst design to device construction.

Authors:  Masaaki Sadakiyo; Shinichi Hata; Takashi Fukushima; Gergely Juhász; Miho Yamauchi
Journal:  Phys Chem Chem Phys       Date:  2019-03-13       Impact factor: 3.676

9.  Carbon-neutral energy cycles using alcohols.

Authors:  Takashi Fukushima; Sho Kitano; Shinichi Hata; Miho Yamauchi
Journal:  Sci Technol Adv Mater       Date:  2018-02-15       Impact factor: 8.090
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