Literature DB >> 34213041

Catalytic Reduction of N2 to Borylamine at a Molybdenum Complex.

Soukaina Bennaamane1, Maria Espada2, Andrea Mulas3, Théo Personeni3, Nathalie Saffon-Merceron4, Marie Fustier-Boutignon2, Christophe Bucher3, Nicolas Mézailles5.   

Abstract

Catalytic formation of borylamines from atmospheric N 2 is achieved for the first time using a series of homogenous (triphosphine)Mo complexes. Stepwise functionnalization of the (triphosphine)Mo-nitrido complex with chloroborane led the synthesis of the imido complex. Electrochemical characterization of the (PPP)Mo-nitrido and (PPP)Mo-borylimido complexes showed that the latter is much more easily reduced.
© 2021 Wiley-VCH GmbH.

Entities:  

Keywords:  Molybdenum; N2 reduction; boranes; nitride functionalization; tridentate phosphine ligands

Year:  2021        PMID： 34213041     DOI： 10.1002/anie.202106025

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Rhenium-Mediated Conversion of Dinitrogen and Nitric Oxide to Nitrous Oxide.

Authors:  Lukas Alig; Kim A Eisenlohr; Yaroslava Zelenkova; Sven Rosendahl; Regine Herbst-Irmer; Serhiy Demeshko; Max C Holthausen; Sven Schneider
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-02       Impact factor: 16.823

2.  Molybdenum-Mediated N2 -Splitting and Functionalization in the Presence of a Coordinated Alkyne.

Authors:  Hannah K Wagner; Hubert Wadepohl; Joachim Ballmann
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-03       Impact factor: 16.823

3.  Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation.

Authors:  Shogo Kuriyama; Shenglan Wei; Takeru Kato; Yoshiaki Nishibayashi
Journal:  Molecules       Date:  2022-04-06       Impact factor: 4.411

4.  Photoelectrochemical Conversion of Dinitrogen to Benzonitrile: Selectivity Control by Electrophile- versus Proton-Coupled Electron Transfer.

Authors:  Maximilian Fritz; Severine Rupp; Ciara I Kiene; Sesha Kisan; Joshua Telser; Christian Würtele; Vera Krewald; Sven Schneider
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-18       Impact factor: 16.823
  4 in total

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