Linear/Ladder-Like Polysiloxane Block Copolymers with Methyl-, Trifluoropropyl- and Phenyl- Siloxane Units for Surface Modification.

Multiblock copolymers containing linear polydimethylsiloxane or polymethyltrifluoropropylsiloxane and ladder-like polyphenylsiloxane were synthesized in a one-step pathway. The functional homopolymer blocks and final multiblock copolymers were characterized using solution and solid-state multinuclear 1H, 13C, 19F, and 29Si NMR spectroscopy. It was shown that the ladder-like block contains silanol units, which influence the adhesion properties of multiblock copolymers and morphology of their casted films. The adhesion to metals and mechanical properties of multiblock copolymers were tested. The SEM study of casted films of multiblock copolymers shows the variety of formed morphologies, including long-strip-like or globular.