Literature DB >> 34186526

Correct scaling of the correlation length from a theory for concentrated electrolytes.

A Ciach1, O Patsahan2.   

Abstract

Self-consistent theory for concentrated electrolytes is developed. Oscillatory decay of the charge-charge correlation function with the decay length that shows perfect agreement with the experimentally discovered and so far unexplained scaling is obtained. For the density-density correlations, monotonic asymptotic decay with the decay length comparable with the decay length of the charge correlations is found. We show that the correlation lengths in concentrated electrolytes depend crucially on the local variance of the charge density.
© 2021 IOP Publishing Ltd.

Keywords:  correlation length in concentrated electrolytes; effects of fluctuations; structure of ionic liquid mixtures

Year:  2021        PMID: 34186526     DOI: 10.1088/1361-648X/ac0f9e

Source DB:  PubMed          Journal:  J Phys Condens Matter        ISSN: 0953-8984            Impact factor:   2.333


  1 in total

1.  Mesoscopic Inhomogeneities in Concentrated Electrolytes.

Authors:  Oksana Patsahan; Alina Ciach
Journal:  ACS Omega       Date:  2022-02-16
  1 in total

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