Literature DB >> 34182671

N5 +: A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material.

Karl O Christe1, William W Wilson1, Jeffrey A Sheehy1, Jerry A Boatz1.   

Abstract

Only the third known example of a homoleptic polynitrogen species besides N2 and N3 -, the N5 + ion possesses surprising stability and can be isolated on a macroscopic scale as its AsF6 - salt. The assigment of the C2v-symmetric structure (shown schematically) predicted by calculations was supported by IR and Raman as well as 14N and 15N NMR spectroscopic studies of the isotopically labeled product. © 1999 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Density functional calculations; Isotopic labeling; NMR spectroscopy; Nitrogen; Vibrational spectroscopy

Year:  1999        PMID： 34182671     DOI： 10.1002/(SICI)1521-3773(19990712)38:13/14<2004::AID-ANIE2004>3.0.CO;2-7

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  9 in total

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4.  Hydrogen Bond and π-π Stacking Interaction: Stabilization Mechanism of Two Metal Cyclo-N5 --Containing Energetic Materials.

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