| Literature DB >> 34182668 |
Herbert C Brown1, Guang-Ming Chen1, Michael P Jennings1, P Veeraraghavan Ramachandran1.
Abstract
A Markovnikov regioselectivity of 92 % or higher is achieved in the hydroboration of a series of perfluoroalkylethylenes and 2',3',4',5',6'-pentafluorostyrene with dichloro- and dibromoborane to provide the corresponding (fluoroalkyl)dihaloboranes (see reaction). © 1999 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.Entities:
Keywords: Boranes; Fluoroalkenes; Hydroborations
Year: 1999 PMID： 34182668 DOI： 10.1002/(SICI)1521-3773(19990712)38:13/14<2052::AID-ANIE2052>3.0.CO;2-9
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336