Adsorptive removal of Pb(II) ions onto surface modified adsorbents derived from Cassia fistula seeds: Optimization and modelling study.

Cassia fistula seeds has been utilized for the abstraction of Pb(II) ions from the aqueous environment. Raw Cassia fistula seeds (RCF) and three different surface modified (physically treated - PMCF and chemically treated - HMCF and SMCF) adsorbent material were taken for investigation. The adsorption properties of these materials and their contact amongst the Pb(II) ion and sorbent materials were characterized by FTIR and SEM analysis. The parameters influencing the adsorption capacity of varied adsorbents were evaluated: maximum solution pH for Pb(II) is 5.0; interactive time is 30 min; dosage is 8.0 g/L for RCF, 4.0 g/L for HMCF, 2.5 g/L for PMCF and 1.0 g/L for SMCF. The modelling study reveals that Freundlich isotherm and Pseudo first order kinetics fits well and the utmost adsorption measurements for the varied adsorbents were found to be 13.22, 28.28, 48.66 and 129.3 mg/g, respectively.