Ruthenium-Nanoparticle-Loaded Hollow Carbon Spheres as Nanoreactors for Hydrogenation of Levulinic Acid: Explicitly Recognizing the Void-Confinement Effect.

As a typical class of man-made nanoreactors, metal-loaded hollow carbon nanostructures (MHC nanoreactors) exhibit competitive potentials in the heterogeneous catalysis due to their tailorable microenvironment effects, in which the void-confinement effect is one of the most fundamental functions in boosting the catalytic performance. Herein this paper, Ru-loaded hollow carbon spheres are employed as nanoreactors with a crucial biomass hydrogenation process, levulinic acid (LA) hydrogenation into γ-valerolactone, as the probe reaction to further recognize the forming mechanism of this pivotal effect. We demonstrated that the void-confinement effect of the selected MHC nanoreactors is essentially driven by an integrating action of electronic metal-support interaction, reactant enrichment and diffusion, which are mainly ascribed to peculiar properties of hollow nanoreactors both in electronic and structural aspects, respectively. This work offers a distinct case for interpreting the catalytic behaviour of MHC nanoreactors, which could potentially promise broader insights into the microenvironment engineering strategies of hollow nanostructures.