Lisman Suryanegara 1 , Widya Fatriasari 1 , Deni Zulfiana 1 , Sita Heris Anita 1 , Nanang Masruchin 1 , Sesmi Gutari 2 , Tetty Kemala 2 Show Affiliations »
Abstract
PURPOSE: The purpose of this study was to develop antimicrobial bioplastics based on Poly Lactic Acid (PLA) with the addition of chitosan-ZnO, and chitosan-TiO2 to improve antimicrobial properties. METHODS: For the preparation of the bioplastics, PLA with chitosan-ZnO or chitosan-TiO2 were used. The antimicrobial activity, mechanical and thermal properties, and water vapor permeability of bioplastics were evaluated. RESULTS: PLA-chitosan-ZnO indicated a robust antimicrobial activity against bacteria such as Salmonella typhi, Bacillus subtilis, Escherichia coli, Staphylococcus aureus, yeast such as Candida albicans, and fungus Aspergillus niger. No formation of new functional groups in PLA-chitosan-ZnO composites. In comparison to other PLA-based bioplastics, this bioplastic has medium tensile strength, tensile modulus, and elongation percentages with low barrier ability to water vapor. Chitosan-ZnO itself has a greater tensile strength compared to chitosan-TiO2. These two compounds undergo 2 stages of decomposition in a temperature range of 43 °C to 265 °C. The addition of PLA into chitosan-ZnO or chitosan TiO2 causes the bioplastics decomposed in a single stage. It also increases the decomposition temperature of bioplastic. However, compared to chitosan-ZnO or TiO2, the PLA-chitosan-ZnO or TiO2 bioplastics tend to produce a fragile composite indicating by decrease in their tensile strength. CONCLUSION: In general, the addition of chitosan-ZnO into in PLA-based bioplastic produces better antimicrobial properties compared to TiO2. © Springer Nature Switzerland AG 2021.
PURPOSE: The purpose of this study was to develop antimicrobial bioplastics based on Poly Lactic Acid (PLA) with the addition of chitosan-ZnO, and chitosan-TiO2 to improve antimicrobial properties. METHODS: For the preparation of the bioplastics, PLA with chitosan-ZnO or chitosan-TiO2 were used. The antimicrobial activity, mechanical and thermal properties, and water vapor permeability of bioplastics were evaluated. RESULTS: PLA-chitosan-ZnO indicated a robust antimicrobial activity against bacteria such as Salmonella typhi, Bacillus subtilis, Escherichia coli, Staphylococcus aureus, yeast such as Candida albicans, and fungus Aspergillus niger. No formation of new functional groups in PLA-chitosan-ZnO composites. In comparison to other PLA-based bioplastics, this bioplastic has medium tensile strength, tensile modulus, and elongation percentages with low barrier ability to water vapor. Chitosan-ZnO itself has a greater tensile strength compared to chitosan-TiO2. These two compounds undergo 2 stages of decomposition in a temperature range of 43 °C to 265 °C. The addition of PLA into chitosan-ZnO or chitosan TiO2 causes the bioplastics decomposed in a single stage. It also increases the decomposition temperature of bioplastic. However, compared to chitosan-ZnO or TiO2, the PLA-chitosan-ZnO or TiO2 bioplastics tend to produce a fragile composite indicating by decrease in their tensile strength. CONCLUSION: In general, the addition of chitosan-ZnO into in PLA-based bioplastic produces better antimicrobial properties compared to TiO2. © Springer Nature Switzerland AG 2021.
Entities: Chemical
Keywords:
Antimicrobial properties; Bioplastic; Chitosan; Poly lactic acid (PLA); TiO2; ZnO
Year: 2021
PMID： 34150245 PMCID： PMC8172708 DOI： 10.1007/s40201-021-00614-z
Source DB: PubMed Journal: J Environ Health Sci Eng